PUBLICATIONS

Reviews, Articles, and Patents:

  1. Three or Four Heteroatoms Including At Least One Other Element. Nemykin, V. N. Chapter 5.24C in: Comprehensive Heterocycle Chemistry , 2008 , in press.

  2. Preparation, characterization, and circularly polarized luminiscence of lanthanum and europuim 1,1'-binaphthyl-2,2'-diyl phosphate complexes. Pedziwiatr, M.; Kosareff, N. M.; Muller, G.; Koposov, A. Y.; Nemykin, V. N.; Riehl, J. P.; Legendziewicz, J. J. Alloys Comp. 2007 , in press .
  3. Influence of Molecular Geometry, Exchange-Correlation Functional, and Solvent Effects in the Modeling of Vertical Excitation Energies in Phthalocyanines Using TDDFT and PCM-TDDFT Methods: Can Modern Computational Chemistry Methods Explain Experimental Controversies? Nemykin, V. N.; Hadt, R. G.; Belosludov, R. V.; Mizuseki, H.; Kawazoe, Y. J. Phys. Chem. A 2007 , in press.
  4. Preparation, Characterization, Molecular and Electronic Structures, TDDFT, and TDDFT/PCM Study of the Solvatochromism in Cyanovinylferrocenes. Nemykin, V. N.; Makarova, E. A.; Grosland, J. O.; Hadt, R. G.; Koposov, A. Y. Inorg. Chem. 2007 , ACS ASAP.
  5. Preparation and structure of oligomeric iodosylbenzene sulfate (PhIO)3 . SO3: stable and water-soluble analog of iodosylbenzene. Koposov, A. Y.; Netzel, B. C.; Yusubov M. S; Nemykin, V. N.; Nazarenko, A. Y.; Zhdankin, V. V. Eur. J. Org. Chem. 2007 , 4475-4478.
  6. A copper-catalyzed domino radical cyclization route to benzospiro-indolizidinepyrrolidinones. Stevens, C. V.; Van Meenen, E.; Masschelein, K. G. R.; Eeckhout, Y.; Hooghe, W.; D'Hondt, B.; Nemykin, V. N.; Zhdankin, V. V. Tetr. Lett. 2007 , 48 , 7108-7111.
  7. Mixed-valence states formation in conformationally flexible metal-free 5,10,15,20-tetraferrocenylporphyrin and 5,10-bisferrocenyl-15,20-bisphenylporphyrin. Nemykin, V. N.; Barrett, C. D.; Hadt, R. G.; Subbotin, R. I.; Maximov, A. Y.; Polshin, E. V.; Koposov, A. Y. Dalton Trans. 2007 , 3378-3389.
  8. Preparation and characterization of first optically active rigid phthalocyanine dimers. Nemykin, V. N.; Koposov, A. Y.; Subbotin, R. I.; Sharma, S. Tetr. Lett. 2007 , 48 , 5425-5428.
  9. Mercury-Free Preparation, Characterization, and Molecular Structure of Tricyanovinylferrocene Using an Unusual Reaction between Ferrocene and Tetracyanoethylene. Nemykin, V. N.; Maximov, A. Y.; Koposov, A. Y. Organometallics 2007 , 26 , 3138-3148.
  10. Preparation, characterization, and catalytic activity of synthetic carbon-supported (phthalocyaninato)cobalt-containing complexes in dodecane-1-thiol oxidation reaction. Nemykin, V. N.; Polshyna, A. E.; Borisenkova, S. A.; Strelko, V. V. J. Mol. Cat. A: Chemical 2007 , 264 , 103-109.
  11. Synthesis, Molecular and Electronic Structure, and TDDFT and TDDFT-PCM Study of the Solvatochromic Properties of (Me2Pipdt)Mo(CO)4 Complex (Me2Pipdt = N,N'-Dimethylpiperazine-2,3-dithione). Nemykin, V. N.; Olsen, J. G.; Perera, E.; Basu, P. Inorg. Chem. 2006 , 45 , 3557 - 3568.
  12. The pyroglutamate hydantoin rearrangement. Dieltiens, N.; Claeys, D. D.; Zhdankin, V. V.; Nemykin, V. N.; Allaert, B.; Verpoort, F.; Stevens, C. V. Eur. J. Org. Chem. 2006 , 2649 – 2660.
  13. Influence of Hartree-Fock Exchange on the Calculated Moessbauer Isomer Shifts and Quadrupole Splittings in Ferrocene Derivatives Using Density Functional Theory. Nemykin, V. N.; Hadt, R. G. Inorg. Chem. 2006 , 45 , 8297 - 8307.
  14. 2-Iodylphenol Ethers: Preparation, X-ray Crystal Structure, and Reactivity of New Hypervalent Iodine(V) Oxidizing Reagents. Koposov, A. Y.; Karimov, R. R.; Geraskin, I. M.; Nemykin, V. N.; Zhdankin, V. V. J. Org. Chem. 2006 , 71 , 8452 - 8458.
  15. Synthesis, spectroscopy, and theoretical modeling of mixed-valence states in polyferrocenyl-containing porphyrins and tetraazaporphyrins. Nemykin, V. N.; Maximov, A. Y.; Barrett, C.; Koposov, A. Y.; McGinn, M.; Loim, N. M.; Breggren, T. J. Porph. Phthalocyan. 2006 , 10 , 490.
  16. Modeling of the vertical excitation energies in the structural isomers of pyridinoporphyrazines and their structural analogues using TDDFT, PCM-TDDFT, ZINDO/S, and PM3 methods. Nemykin, V. N.; Belosludov, R. V.; Mizuseki, H.; Kawazoe, Y. J. Porph. Phthalocyan. 2006 , 10 , 792.
  17. An investigation of the catalytic degradation of the soluble m -(oxo)dimeric iron phthalocyanine in non-coordinating solvents: spectroscopic and theoretical evidence for the formation of Fe IV -O-Fe IV core. Nemykin, V. N.; Addei-Maanu, C.; Koposov, A. Y.; Tretyakova, I. N.; Polshyn, E. V. J. Porph. Phthalocyan. 2006 , 10 , 793.
  18. Synthesis, Structure, and Chemoselective Reactivity of N-(2-Iodylphenyl)acylamides: Hypervalent Iodine Reagents Bearing a Pseudo Six-Membered Ring Scaffold. Ladziata, U.; Koposov, A. Y.; Lo, K. Y.; Willing, J.; Nemykin, V. N.; Zhdankin, V. V. Angew. Chem. Int. Ed. 2005 , 44 , 7127 -7131.
  19. Accessing of the Mixed-Valence States in the Zinc Meso-Ferrocenylporphyrin: Experimental and Theoretical Data. Nemykin, V. N.; McGinn, M.; Koposov, A. Y.; Tretyakova, I. N.; Polshin, E. V.; Loim, N. M.; Abramova, N. V. Ukr. Khim. Zh. 2005 , 69 , 79 – 85.
  20. Oxomolybdenum Tetrathiolates with Sterically Encumbering Ligands: Modeling the Effect of a Protein Matrix on Electronic Structure and Reduction Potentials. McNaughton, R. L.; Mondal, S.; Nemykin, V. N.; Basu, P.; Kirk, M. L. Inorg. Chem. 2005 , 44 , 8216-8222.
  21. Oxygen Atom Transfer Reactivity from a Dioxo-Mo(VI) Complex to Tertiary Phosphines: Synthesis, Characterization, and Structure of Phosphoryl Intermediate Complexes. Nemykin, V. N.; Basu, P. Inorg. Chem. 2005 , 44 , 7494-7502.
  22. Intra- and intermolecular interactions in the solid state structure of 2-iodylbenzenesulfonamides: a heptacoordinated organic iodine(v) compound. Koposov, A. Y.; Nemykin, V. N.; Zhdankin, V. V. New J. Chem. 2005 , 29 , 998-1000.
  23. Oxygen atom transfer in models for molybdenum enzymes: Isolation and structural, spectroscopic, and computational studies of intermediates in oxygen atom transfer from molybdenum(VI) to phosphorus(III). Millar, A. J.; Doonan, C. J.; Smith, P. D.; Nemykin, V. N.; Basu, P.; Young, C. G. Chem. Eur. J. 2005 , 11 , 3255-3267.
  24. Pentaaquadisodium bis(triphenylcyanoborate) (caesignost). Nazarenko, A. Y.; Nemykin, V. N. Acta Cryst. 2005 , E61 , m2317-m2319.
  25. Energy-Dependent Electrospray Ionization Mass Spectrometric Studies of Mononuclear Metal Carbonyls. Nemykin, V. N.; Basu, P. Inorg. Chim. Acta 2005 , 358 , 2876-2882.
  26. Isolation, Characterization of an Intermediate in an Oxygen Atom-Transfer Reaction, and the Determination of the Bond Dissociation Energy. Nemykin, V. N.; Laskin, J.; Basu, P. J. Am. Chem. Soc. 2004 , 126 , 8604-8605.
  27. A bifurcated pathway of oxygen atom transfer reactions from a monooxo molybdenum(VI) complex under electrospray ionization mass spectrometric conditions. Nemykin, V. N. ; Basu, P. Dalton Transactions 2004 , 1928-1933.
  28. Synthesis, spectroscopy, and redox chemistry of encapsulated oxo-Mo(V) centers: implications for pyranopterin-containing molybdoenzymes. Basu, P.; Nemykin, V. N.; Sengar, R. Inorg. Chem. 2003 , 42 , 7489-7501.
  29. Donor Atom Dependent Geometric Isomers in Mononuclear Oxo-Molybdenum(V) Complexes: Implications for Coordinated Endogenous Ligation in Molybdoenzymes. Carrano, C. J.; Chohan, B. S.; Hammes, B. S.; Kail, B. W.; Nemykin, V. N.; Basu, P. Inorg. Chem. 2003 , 42, 5999-6007.
  30. A Comparative Theoretical Investigation of the Vertical Excitation Energies and the Electronic Structure of [MoVOCl4] - : Influence of Basis Set and Geometry. Nemykin, V. N.; Basu, P. Inorg. Chem. 2003 , 42 , 4046-4056 .
  31. Electronic Properties of para -Substituted Thiophenols and Disulfides from 13 C NMR Spectroscopy and ab initio Calculations: Relations to the Hammett Parameters and Atomic Charges. Sengar, R. S.; Nemykin, V. N.; Basu, P. New J. Chem. 2003 , 27 , 1115-1123 .
  32. Synthesis of platinum-containing octacarboxylato(phthalocyaninato)zinc. Mytsyk, V. M.; Nemykin, V. N.; Volkov, S. V. Ukr. Khim. Zh. 2003 , 69 , 3-8.
  33. An Analogue System Displaying All the Important Processes of the Catalytic Cycles Involving Monooxomolybdenum(VI) and Desoxomolybdenum(IV) Centers. Nemykin, V. N.; Davie, S. R.; Mondal, S.; Rubie, N.; Kirk, M. L.; Somogyi, A.; Basu, P. J. Am. Chem. Soc. 2002 , 124 , 756-757.
  34. Synthesis, Characterization, Electrochemistry, Electronic Structure, and Isomerization of Mononuclear Oxo-Molybdenum(V) Complexes: The Serine Gate Hypothesis in the Function of DMSO Reductases. Kail, B.; Nemykin, V. N.; Davie, S. R.; Carrano, C. J.; Hammes, B.; Basu, P. Inorg. Chem. 2002 , 41 , 1281-1291.
  35. Adjacent versus Opposite Type Di-Aromatic Ring-Fused Phthalocyanine Derivatives: Synthesis, Spectroscopy, Electrochemistry, and Molecular Orbital Calculations. Kobayashi, N.; Miwa, H.; Nemykin, V. N. J. Am. Chem. Soc. 2002 , 124 , 8007-8020.
  36. A novel hemiporphyrazine comprising three isoindolediimine and three thiadiazole units. Kobayashi, N.; Inagaki, S.; Nemykin, V. N.; Nonomura, T. Angew. Chem., Int. Ed. 2001 , 40 , 2710-2712.
  37. Mössbauer, crystallographic, and density functional theoretical investigation of the electronic structure of bis-ligated low-spin iron (II) phthalocyanines. Nemykin, V. N.; Kobayashi, N.; Chernii, V. Y.; Belsky, V. K. Eur. J. Inorg. Chem. 2001 , 733-743.
  38. The first phthalocyanine-based dimer formed by two pyridine-Pd-pyridine bridges. Kobayashi, N.; Muranaka, A.; Nemykin, V. N. Tetrahedron Lett. 2001 , 42 , 913-915.
  39. A tetraazaporphyrin with an intense, broad near-IR band. Nemykin, V. N.; Kobayashi, Nagao. Chem. Commun. ( Cambridge ) 2001 , 165-166.
  40. Method for production of phthalocyanine and its complexes. Volkov, S. V.; Mytsyk, V. M.; Nemykin, V. N. UKR ?07 D487/22, C07F19/00 Patent written in Ukrainian. 2001.
  41. Diels-alder reaction of tribenzo[b,g,l]thiopheno[3,4-q]porphyrazine as a new path for porphyrazine core modification. Nemykin, V. N.; Polshina, A. E.; Kobayashi, N. Chem. Lett. 2000 , 1236-1237.
  42. Synthesis of novel heteronuclear phthalocyanine complexes of zinc and platinum-photosensitizers of "third generation". Nemykin, V. N.; Myshchyk, V. M. Ukr. Khim. Zh. (Russ. Ed.) 2000 , 66 , 67-70.
  43. Synthesis and spectroscopic properties of new phthalocyanine complexes with potentially combined photodynamic activity and cytotoxicity for photodynamic therapy. Nemykin, V. N.; Mytsyk, V. M.; Volkov, S. V.; Kobayashi, N. J. Porphyrins Phthalocyanines 2000 , 4 , 551-554.
  44. Synthesis, structure and properties of coordination compounds of iron phthalocyanines and their analogues. Nemykin, V. N.; Tret'yakova, I. N.; Volkov, S. V.; Li, V. D.; Mekhryakova, N. G.; Kaliya, Oleg L.; Luk'yanets, Evgenii A. Russ. Chem. Rev. 2000 , 69 , 325-346.
  45. Mixed-ligand complexes of lanthanides with phthalocyanine and its analogues: synthesis, structure, and spectroscopic properties. Nemykin, V. N.; Volkov, S. V. Russ. J. Coord. Chem. 2000 , 26 , 436-450.
  46. The solid phase, room-temperature synthesis of metal-free and metallophthalocyanines, particularly of 2,3,9,10,16,17,23,24-octacyanophthalocyanines. Nemykin, V. N.; Kobayashi, N.; Mytsyk, V. M.; Volkov, S. V. Chem. Lett. 2000 , 546-547.
  47. First direct calculation of the partial quadrupole splitting of ligands for the prediction of Mössbauer spectra parameters in low-spin iron (II) complexes. Nemykin, V. N.; Polshina, A. E.; Polshin, E. V.; Kobayashi, N. Mendeleev Commun. 2000 , 54-56.
  48. Synthesis, properties and Mössbauer spectra of bisaxially co-ordinated iron(II) phthalocyanine low-spin complexes: the first semi-quantitative explanation of the influence of the character of axial ligands on the spectral parameters. Nemykin, V. N.; Polshina, A. E.; Chernii, V. Y.; Polshin, E. V.; Kobayashi, N. Dalton 2000 , 1019-1025.
  49. Low symmetrical phthalocyanines having spectroscopic and electrochemical properties characteristic of unexpected accidental S1 state degeneracy and non-planar distortions. Nemykin, V. N.; Kobayashi, N.; Nonomura, T.; Luk'yanets, E. A. Chem. Lett. 2000 , 184-185.
  50. Solution coordination chemistry of protohemin IX peptide derivatives. Rozhkova, E. A.; Evstigneeva, R. P.; Nemykin, V. N. J. Porphyrins Phthalocyanines 1999 , 3 , 691-702.
  51. Method of calculation of the quadrupole splitting in Mössbauer spectra of axially coordinated iron(II) phthalocyanine complexes. Nemykin, V. N.; Polshina, A. E.; Chernii, V. Y.; Tretyakova, I. N.; Polshin, E. V.; Kobayashi, N. Ukr. Khim. Zh. (Russ. Ed.) 1999 , 65 , 103-108.
  52. Chemochromic properties of mixed-ligand lanthanide phthalocyanine complexes with phthalocyanine cation-radical. Nemykin, V. N.; Mironyuk, T. I.; Zub, V. Ya.; Volkov, S. V. Ukr. Khim. Zh. (Russ. Ed.) 1998 , 64 , 75-79.
  53. Further studies on the oxidation state of iron in m -oxo dimeric phthalocyanine complexes. Nemykin, V. N.; Chernii, V. Ya.; Volkov, S. V.; Bundina, N. I.; Kaliya, O. L.; Li, V. D.; Lukyanets, E. A. V. I. J. Porphyrins Phthalocyanines 1999 , 3 , 87-98.
  54. Synthesis and characterization of polyfluoroalkoxysulfonyl phthalonitriles and corresponding zinc and cobalt phthalocyanines. Kondratenko, N. V.; Tretyakova, I. N.; Luk'yanets, E. A.; Volkov, S. V.; Orlova, R. K.; Nemykin, V. N.; Yagupolskii, L. M. Dyes Pigm. 1999 , 41 , 101-109.
  55. Electronic and Mössbauer spectra of biaxial complexes of iron (II) phthalocyanine with aliphatic and alicyclic amines. Nemykin, V. N.; Chernii, V. Ya.; Pol'shin, E. V.; Kostromina, N. A.; Volkov, S. V. Ukr. Khim. Zh. (Russ. Ed.) 1997 , 63 , 75-84.
  56. Proton NMR study of complexation of iron (II) phthalocyanine with aliphatic amines in solutions. Nemykin, V. N.; Chernii, V. Ya.; Trachevskii, V. V.; Volkov, S. V. Ukr. Khim. Zh. (Russ. Ed.) 1997 , 63 , 3-6.
  57. Synthesis and characterization of new mixed-ligand lanthanide-phthalocyanine cation radical complexes. Nemykin, V. N.; Chernii, Victor Y.; Volkov, Sergey V. J. Chem. Soc., Dalton Trans. 1998 , 2995-3000.
  58. The synthesis and properties of some polyfluoroalkoxy substituted phthalocyanines. Kondratenko, N. V.; Nemykin, V. N.; Lukyanets, E. A.; Kostromina, N. A.; Volkov, S. V.; Yagupolskii, L. M. J. Porphyrins Phthalocyanines 1997 , 1 , 341-347.
  59. Synthesis and spectroscopic characteristics of some mixed-ligand octaphenyltetraazaporphyrin lutetium complexes. Nemykin, V. N.; Kostromina, N. A.; Volkov, S. V. Ukr. Khim. Zh. (Russ. Ed.) 1997 , 63 , 3-6.
  60. Nonplanar distortion modes for C-aminoacyl derivatives of protohemin IX. Evstigneeva, R. P.; Rozhkova, E. A.; Nemykin, V. N.; Voronov, S. A.; Zheltukhina, G. A. Dokl. Akad. Nauk 1997 , 356 , 642-644.
  61. Method for production of phthalocyanine and its complexes. Nemykin, V. N.; Voloshin, Y. Z.; Subbotin, N. B. RU 2061696 C1 19960610 Patent written in Russian. 1996 .
  62. Synthesis and properties of some rare earth 1,2-naphthalocyanines. Nemykin, V. N.; Subbotin, N. B.; Kostromina, N. A.; Volkov, S. V. Ukr. Khim. Zh. (Russ. Ed.) 1995 , 61 , 3-7.
  63. Synthesis and spectra of the mixed-ligand monophthalocyanine complexes of rare-earth elements with bidentate oxygen-containing ligands. Nemykin, V. N.; Tsivadze, A. Yu.; Subbotin, N. B.; Kostromina, N. A.; Volkov, S. V. Russ. J. Coord. Chem. (Transl. of Koord. Khim.) 1996 , 22 , 297-302.
  64. Synthesis and physicochemical properties of highly soluble lanthanide tetra-tert-butyl-2,3-naphthalocyanine complexes. Nemykin, V. N.; Kostromina, N. A.; Subbotin, N. B.; Volkov, S. V. Izv. Akad. Nauk, Ser. Khim. 1996 , 99-102.
  65. Synthesis and study of chemichromic properties of high-soluble dysprosium bis(tetra-tert-butylnaphthalocyaninate). Nemykin, V. N.; Kostromina, N. A.; Volkov, S. V. Izv. Akad. Nauk, Ser. Khim. 1995 , 1963-1965.
  66. Complex compounds of phthalocyanineiron(II) with amines. Kostromina, N. A.; Chernii, V. Ya.; Nemykin, V. N.; Komarov, I. V. Zh. Neorg. Khim. 1995 , 40 , 1491-1495.
  67. Synthesis and properties of asymmetrical dinaphthodibenzoporphyrazine complexes with D2h symmetry of the ligand. Nemykin, V. N.; Subbotin, N. B.; Kostromina, N. A.; Volkov, S. V.; Luk'yanets, E. A. Zh. Neorg. Khim. 1995 , 40 , 1183-1188.
  68. Synthesis of lutetium octaalkylthiotetraazaporphyrins. Nemykin, V. N.; Kostromina, N. A.; Volkov, S. V. Izv. Akad. Nauk, Ser. Khim. 1995 , 572-573.
  69. New, non-symmetrical 2:2 phthalocyanines. 1,2,3,4,15,16,17,18-Octaphenyl-9-23(24)-dinitrophthalo- and 1,2,3,4,19,20,21,22-octaphenyldiphthalo-11,29(30)-di-tert-butyldinaphthalocyanine copper complexes. Nemykin, V. N.; Subbotin, N. B.; Kostromina, N. A.; Volkov, S. V. Mendeleev Commun. 1995 , 71-72.
  70. New selective shift reagents for primary aliphatic amines on the basis of monophthalocyanine lanthanide complexes. Komarov, I.V.; Nemykin, V.N.; Subbotin, N.B. Appl. Magn. Reson. 1993 , 4, 377-382.
  71. A synthesis of novel non-symmetrical phthalocyanines. Subbotin, N. B.; Nemykin, V. N.; Voloshin, Y. Z. Mendeleev Commun. 1993 , 121-122.
  72. Reaction of titanium alkoxides with the N,N-bis(trimethylsilyl)amide-N'-tert-butylimide of thiophosphonic acid. Brusilovets, A. I.; Rusanov, E. B.; Nemykin, V. N. Zh. Obshch. Khim. 1989 , 59 , 1893-1894.

 

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Last Updated October 22, 2007