SCHEDULE OF
EXPERIMENTS
CHEM 2544 -
Organic Chemistry II Laboratory Spring 2013
Laboratory
handouts can be found at: http://www.d.umn.edu/~pgrundt/2544/Handouts.zip
1 Check-in and safety orientation,
introduction to spectroscopy.
2 IR and NMR Spectroscopy, Chapters 11 and
12 - Identification of Unknowns.
3 Oxidation: Cyclohexanone from Cyclohexanol
by Hypochlorite Oxidation, Chapter 22 (Experiment: 5th Edition pp. 381-383; 6th
Edition pp. 361-364)
4 Sodium Borohydride Reduction of
2-Methylcyclohexanone, Chapter 26 (Experiment: 5th Edition pp. 419-423; 6th
Edition pp. 390-394. In both editions skip Computational Chemistry.)
5 Aldehydes and Ketones, Chapter 36.
Unknowns (Experiments: 1, 2, 3, 6, 7. 5th Edition pp. 502-514; 6th Edition pp.
467-478)
6 Esterification, Chapter 40. Synthesis of
n-Butyl Acetate by Azeotropic Distillation of Water (Experiments 1: 5th Edition
pp. 559-560; 6th Edition pp. 520-521)
7 Polymers, Chapter 67 (Experiment 1: 5th
Edition pp. 818-820; 6th Edition pp. 763- 764.)
8 Nitration of Methyl Benzoate, Chapter 28.
(Experiment 1: 5th Edition pp 432-433;
6th Edition pp 402-403)
9 Friedel-Crafts Alkylation of Benzene, Chapter
29 (Experiment 1: 5th Edition pp.
437-440; 6th Edition: pp. 407-410)
10 The Sandmeyer Reaction, Chapter 44
(Experiments 1, 2, 3: 5th Edition pp 596-601; 6th Edition: pp. 554-559)
11 Dyes and Dyeing, Chapter 46. Diazotization
of Sulfanilic Acid and Preparation of Methyl Orange (Experiments 1, 4: 5th
Edition pp. 635-636, 639-640; 6th Edition pp. 592, 596-597.)
12 Amines, Chapter 43 (Experiments: 1 and 2;
5th Edition: 586-590; 6th Edition: 545-548.)
13 Carbohydrates, Chapter 63 (Experiments: 2,
3: 5th Edition: pp. 770-771; 6th
Edition: pp. 723-724.)
14 Check-out