PUBLICATIONS

BOOK CHAPTERS

1.  Victor N. Nemykin and Eugenii A. Lukyanets, "The key role of the peripheral substituents in the chemistry of phthalocyanines", in: Handbook of Porphyrin Science, K. M. Kadish, K. M. Smith and R. Guilard (Eds.); World Scientific: Singapore, 2010, Vol 3, pp 1 - 323 .

2.  Victor N. Nemykin and Paul Kiprof, "Preparation, UV-Vis and MCD spectroscopy, and molecular modeling of zinc phthalocyanine: confirmation of degeneracy of the first excited state", in: The Integrated Approach to Chemistry Laboratory, P. Basu and M. Johnson (Eds); DEStech Publications, Inc: Lancaster, PA, 2009; pp 95 – 105.

3.  Victor N. Nemykin, "Three or Four Heteroatoms including at least One Other Element", in: Comprehensive Heterocyclic Chemistry III, A. R. Katritzky, C. A. Ramsden, E. F. V. Scriven and R. J. K. Taylor (Eds.); Elsevier: Oxford, 2008; Vol. 6, pp 691 - 738.

 

RESEARCH PAPERS

Research papers since at UMD (2004 - current)

1  Yusubov, M. S.; Yusubova, R. Y.; Nemykin, V. N.; Maskaev, A. V.; Geraskina, M. R.; Kirschning, A.; Zhdankin, V. V. “Potassium 4-iodylbenzenesulfonate: preparation, structure, and application as a reagent for oxidative iodination of arenes”. Eur. J. Org. Chem. 2012, in press, DOI: 10.1002/ejoc.201201064.

2  Sabin, J. R.; Varzatskii, O. A.; Voloshin, Y. Z.; Starikova, Z. A.; Novikov, V. V.; Nemykin, V. N. “Insight into the Electronic Structure, Optical Properties, And Redox Behavior of the Hybrid Phthalocyaninoclathrochelates from Experimental and Density Functional Theory Approaches”. Inorg. Chem., 2012, 51, 8362-8372.

3  Pimkov, I. V.; Nigam, A.; Venna, K.; Fleming, F. F.; Solntsev, P. V.; Nemykin, V. N.; Basu, P. "Dithiolopyranthione Synthesis, Spectroscopy and an Unusual Reactivity with DDQ". J. Heterocyclic Chem., 2012, accepted .

4  Nemykin, V. N.; Chen, P.; Solntsev, P. V.; Purchel, A. A.; Kadish, K. M. “Characterization of the unusual metal-free, zinc, chloroindium, and ferrocenylindium 5,10,15,20-tetraferrocenylporphyrin anion-radicals by spectroelectrochemical, DFT, and TDDFT approaches”. J. Porphyrins Phthalocyanines 2012, 16, 793-801 (invited paper for special issue).

5  Yoshimura, A.; Middleton, K. R.; Zhu, C.; Nemykin, V. N.; Zhdankin, V. V. “Hypoiodite-Mediated Metal-Free Catalytic Aziridination of Alkenes”. Angew. Chem., Int. Ed., 2012, 51, 8059-8062 .

6  Ziegler, C. J.; Nemykin, V. N. “2,5-Diaminothiophene-3,4-dicarbonitrile”. Acta Cryst. E, 2012, E68, o2693.

7  Nemykin, V. N.; Sabin, J. R. “Profiling Energetics and Spectroscopic Signatures in Prototropic Tautomers of Asymmetric Phthalocyanine Analogues”. J. Phys. Chem. A, 2012, 116, 7364-7371.

8  Solntsev, P. V.; Spurgin, K. L.; Sabin, J. R.; Heikal, A. A.; Nemykin, V. N. “Photoinduced Charge Transfer in Short-Distance Ferrocenylsubphthalocyanine Dyads”. Inorg. Chem. 2012, 51, 6537-6547.

9  Zhu, C.; Yoshimura, A.; Ji, L.; Wei, Y.; Nemykin, V. N.; Zhdankin, V. V. “Design, Preparation, X-ray Crystal Structure, and Reactivity of o-Alkoxyphenyliodonium Bis(methoxycarbonyl)methanide, a Highly Soluble Carbene Precursor”. Org. Lett. 2012, 14, 3170-3173.

10  Vecchi, A.; Gatto, E.; Floris, B.; Conte, V.; Venanzi, M.; Nemykin, V. N.; Galloni, P. “Tetraferrocenylporphyrins as active components of self-assembled monolayers on gold surface”. Chem. Commun., 2012, 48, 5145-5147 (invited paper for themed issue).

11  Marcano, D.; Gerasimchuk, N.; Nemykin, V.; Silchenko, S. “Synthesis, Characterization, and Studies of Coordination-Polymers With Isomeric Pyridylcyanoximes: Route to Metal Ribbons With Very Short Tl•••Tl Separations”. Cryst. Growth Design 2012, 12, 2877-2889.

12  Ziegler, C. J.; Sabin, J. R.; Geier, G. R.; Nemykin, V. N. “The first TDDFT and MCD studies of free base triarylcorroles: A closer look into solvent-dependent UV-visible absorption”. Chem. Commun. , 2012, 48, 4743-4745 (invited paper for themed issue).

13  Nemykin, V. N.; Polshyna, A. E.; Makarova, E. A.; Kobayashi, N.; Lukyanets, E. A. “Unexpected formation of the nickel seco-tribenzoporphyrazine with a tribenzotetraazachlorin-type absorption spectrum”. Chem. Commun., 2012, 48, 3650–3652 (invited paper for themed issue).

14  Ratcliff, J.; Kuduk-Jaworska, J.; Chojnacki, H.; Nemykin, V.; Gerasimchuk, N. “Part 1: Experimental and theoretical studies of 2-cyano-2-isonitroso-N-piperidynylacetamide (HPiPCO), 2-cyano-2-isonitroso-N-morpholylacetamide (HMCO) and their Pt- and Pd-complexes”. Inorg. Chim. Acta., 2012, 385, 1-11.

15  Zhu, C.; Yoshimura, A.; Wei, Y.; Nemykin, V. N.; Zhdankin, V. V. “Facile preparation and reactivity of bifunctional ionic liquid-supported hypervalent iodine reagent: a convenient recyclable reagent for catalytic oxidation”. Tetrahedron Lett., 2012, 53, 1438-1444.

16  Doboszewski, B.; De Silva, M. J.; Nazarenko, A. Y.; Nemykin, V. N. “3-Deoxy-1,2-di-O-isopropylidene-5-O-tosyl-d-threo-pentofuranose”. Acta Cryst., Section E: Structure Reports Online 2012, E68, o1109-o1110.

17  Solntsev, P. V.; Goetsch, W. R.; Nemykin, V. N. “Formation of an Unexpected Organometallic Mercury Compound in a Palladium-Catalyzed Reaction”. Organometallics, 2011, 30, 6636-6640.

18  Solntsev, P. V.; Neisen, B. D.; Sabin, J. R.; Gerasimchuk, N. N.; Nemykin, V. N. “Synthesis, characterization, X-ray structure, and mixed-valence states of trans -dichlorotin(IV)-5,10,15,20-tetraferrocenylporphyrin”. J. Porphyrins Phthalocyanines, 2011, 15, 612-621 (invited paper for special issue).

19  Nazarenko A. Y.; Nemykin, V. N. “Crystal Data behind Efficient Cesium Recognition: Triphenylcyanoborates of Potassium, Rubidium, and Cesium”. CrystEngComm, 2011, 13, 6352-6355.

20  Nemykin, V. N.; Maskaev, A. V.; Geraskina, M. R.; Yusubov, M. S.; Zhdankin, V. V. “Preparation and X-ray crystal study of benziodoxaborole derivatives: new hypervalent iodine heterocycles”. Inorg. Chem., 2011, 50, 11263-11272.

21  Yoshimura, A.; Nemykin, V. N.; Zhdankin, V. V. “o-Alkoxyphenyliminoiodanes: Highly Efficient Reagents for the Catalytic Aziridination of Alkenes and the Metal-Free Amination of Organic Substrates”, Chem. Eur. J., 2011, 17, 10538-10541.

22  Sripothongnak, S.; Ziegler, C. J.; Dahlby, M. R.; Nemykin, V. N. “Controllable and Reversible Inversion of the Electronic Structure in Nickel N-Confused Porphyrin: A Case When MCD Matters”. Inorg. Chem., 2011, 50, 6902-6909 .

23  Rohde, G. T.; Sabin, J. R.; Barrett, C. D.; Nemykin, V. N. “Long-range metal–metal coupling in transition-metal 5,10,15,20-tetraferrocenylporphyrins”. New J. Chem., 2011, 35, 1440-1448.

24  Solntsev, P. V.; Dudkin, S. V.; Sabin, J. R.; Nemykin, V. N. “Electronic Communications in (Z)-Bis(ferrocenyl)ethylenes with Electron-Withdrawing Substituents”. Organometallics, 2011, 30, 3037-3046.

25  Yoshimura, A.; Banek, C. T.; Yusubov, M. S.; Nemykin, V. N.; Zhdankin, V. V. “Preparation, X-ray Structure, and Reactivity of 2-Iodylpyridines: Recyclable Hypervalent Iodine(V) Reagents”. J. Org. Chem., 2011, 76, 3812-3819.

26  Doboszewski, B.; Nazarenko, A. Y.; Nemykin, V. N. “3'-O-Acetyl-2'-deoxyuridine”. Acta Cryst. 2011, E67, o3-o4.

27  Doboszewski, B.; de Toni Uchoa, F.; Nazarenko, A. Y.; Nemykin, V. N. “Crystal structure of 1-deoxy-1-(3-hydroxypropyl)-O-triphenylmethyl- b -D-lyxofuranose, C27H30O5 ”. Z. Kristallogr. NCS 2011, 226, 61-62.

28  Nemykin, V. N.; Hadt, R. G. “ Interpretation of the UV-Vis spectra of the meso(ferrocenyl)-containing porphyrins using TDDFT approach: is Gouterman's classic four-orbital model still in play?”. J. Phys. Chem. A 2010, 114, 12062-12066.

29  Neu, H. M.; Zhdankin, V. V.; Nemykin, V. N. “Binuclear iron(III) phthalocyanine( m -oxodimer)/tetrabutylammonium oxone: a powerful catalytic system for oxidation of hydrocarbons in organic solution”. Tetr. Lett. 2010, 51, 6545-6548.

30  Nemykin, V. N.; Rohde, G. T.; Barrett, C. D.; Hadt, R. G.; Sabin, J. R.; Reina, G.; Galloni, P.; Floris, B. "Long-range electronic communication in free-base meso -poly(ferrocenyl)-containing porphyrins". Inorg. Chem. 2010, 49, 7497-7509.

31  Solntsev, P. V.; Sabin, J. R.; Dammer, S. J.; Gerasimchuk, N. N.; Nemykin, V. N. “Unexpected fluorescence properties  in the axially s -bonded ferrocenyl-containing porphyrin”. Chem. Commun. 2010, 6581-6583.

32  Basu, P.; Nigam, A.; Mogesa, B.; Denti, S.; Nemykin, V. N. “Synthesis, characterization, spectroscopy, electronic and redox properties of a new nickel dithiolene system”. Inorg. Chim. Acta, 2010, 363, 2857-2864.

33  Yusubov, M. S.; Nemykin, V. N.; Zhdankin, V. V. “Transition metal-mediated oxidations utilizing monomeric iodosyl- and iodylarene species”. Tetrahedron 2010, 66, 5745-5752.

34  Yoshimura, A.; Neu, H. M.; Nemykin, V. N.; Zhdankin, V. V. “Metalloporphyrin/Iodine(III)-Cocatalyzed Oxygenation of Aromatic Hydrocarbons”. Adv. Synth. Catal. 2010, 352, 1455-1460.

35  Grundt, P.; Douglas, K. A.; Krivogorsky, B.; Nemykin, V. N. “7,9-Dichloro-6H,12H-indolo[2,1-b]quinazoline-6,12-dione”. Acta Cryst., 2010, E66, o1474-o1475.

36  Nemykin, V. N.; Lukyanets, E. A. “Synthesis of substituted phthalocyanines”. ARKIVOC 2010, i, 136-208.

37  Lukyanets, E. A., Nemykin, V. N. " The key role of peripheral substituents in the chemistry of phthalocyanines and their analogs". J. Porphyrins Phthalocyanines 2010, 14, 1 - 40.

38  Doboszewski, B.; da Silva, P. R.; Nazarenko, A. Y.; Nemykin, V. N. “6-[Bis(ethoxycarbonyl)methyl]-6-deoxy-1,2;3,4-di- O -isopropylidene-D-galactopyranose”. Acta Cryst. 2010, E66, o3217-o3218.

39 Neu, H. M.; Yusubov, M. S.; Zhdankin, V. V.; Nemykin, V. N. "Binuclear iron(III) phthalocyanine(µ-oxo-dimer)-catalyzed oxygenation of aromatic hydrocarbons with iodosylbenzene sulfate and iodosylbenzene as the oxidants". Adv. Synth. Catal. 2009, 351, 3168-3174.

40  Hadt, R. G.; Nemykin, V. N.; Olsen, J. G.; Basu, P. "Comparative calculation of EPR spectral parameters in [MoVOX4]- , [MoVOX5]2- , and [MoVOX4 (H2O)]- complexes". Phys. Chem. Chem. Phys. 2009, 11, 10377-10384.

41  Mailyan, A. K.; Geraskin, I. M.; Nemykin, V. N.; Zhdankin, V. V. " Preparation, X-ray Structure, and Oxidative Reactivity of N-(2-Iodylphenyl)tosylamides and 2-Iodylphenyl Tosylate: Iodylarenes Stabilized by Ortho-Substitution with a Sulfonyl Group". J. Org. Chem. 2009, 74, 8444-8447.

42  Nemykin, V. N.; Rohde, G. T.; Barrett, C. D.; Hadt, R. G.; Bizzarri, C.; Galloni, P.; Floris, B.; Nowik, I.; Herber, R. H.; Marrani, A. G.; Zanoni, R.; Loim, N. M. " Electron-Transfer Processes in Metal-Free Tetraferrocenylporphyrin. Understanding Internal Interactions To Access Mixed-Valence States Potentially Useful for Quantum Cellular Automata". J. Am. Chem. Soc. 2009, 131, 14969-14978.

43  Dorweiler, J. D.; Nemykin, V. N.; Ley, A. N.; Pike, R. D.; Berry, S. M. " Structural and NMR characterization of Sm(III), Eu(III), and Yb(III) Complexes of an amide based polydentate ligand exhibiting Paramagnetic Chemical Exchange Saturation Transfer abilities". Inorg. Chem. 2009, 48, 9365-9376.

44  Basu, P.; Nemykin, V. N.; Sengar, R. S. " Substituent Effect on Oxygen Atom Transfer Reactivity from Oxomolybdenum Centers: Synthesis, Structure, Electrochemistry, and Mechanism". Inorg. Chem. 2009, 48, 6303-6313.

45  Nemykin, V. N.; Koposov, A. Y.; Netzel, B. C.; Yusubov, M. S.; Zhdankin, V. V. " Self-Assembly of Hydroxy(phenyl)iodonium Ions in Acidic Aqueous Solution: Preparation, and X-ray Crystal Structures of Oligomeric Phenyliodine(III) Sulfates". Inorg. Chem. 2009, 48, 4908-4917.

46  Geraskin, I. M.; Pavlova, O.; Neu, H. M.; Yusubov, M. S.; Nemykin, V. N.; Zhdankin, V. V. " Comparative reactivity of hypervalent iodine oxidants in metalloporphyrin-catalyzed oxygenation of hydrocarbons: iodosylbenzene sulfate and 2-iodylbenzoic acid ester as safe and convenient alternatives to iodosylbenzene". Adv. Synth. Catal. 2009, 351, 733-737.

47  Hadt, R. G.; Nemykin, V. N. " Exploring the Ground and Excited State Potential Energy Landscapes of the Mixed-Valence Biferrocenium Complex". Inorg. Chem. 2009, 48, 3982-3992.

48  Nemykin, V. N.; Dorweiler, J. D.; Subbotin, R. I. " Ferrocenylbutadiyne'" Acta Cryst., Sec. E: Structure Reports Online 2009, E65, m298-m299, m298/1-m298/7.

49  Zhdankin, V. V.; Nemykin, V. N.; Karimov, R. R.; Kazhkenov, Z.-G. " Preparation and X-ray crystal structure of 2-iodyl-N,N-dialkylaniline oxides: first entry into the heterocyclic system of benziodoxazole". Chem. Commun. 2008, 6131-6133 .

50  Geraskin, I. M.; Luedtke, M. W.; Neu, H. M.; Nemykin, V. N.; Zhdankin, V. V. " Organic iodine(V) compounds as terminal oxidants in iron(III) phthalocyanine catalyzed oxidation of alcohols". Tetr. Lett. 2008, 49, 7410-7412 .

51  Ilkun, O. T.; Archibald, S. J.; Barnes, C. L.; Gerasimchuk, N.; Biagioni, R.; Silchenko, S.; Gerasimchuk, O. A.; Nemykin, V. N. " Benz(2-heteroaryl)cyanoximes and their Tl(I) complexes: new room temperature blue emitters". Dalton Trans. 2008, 5715-5729 .

52  Claeys, D. D.; Moonen, K.; Roman, B. I.; Nemykin, V. N.; Zhdankin, V. V.; Waroquier, M.; Van Speybroeck, V.; Stevens, C. V. " Synthesis of Tricyclic Phosphonopyrrolidines via IMDAF: Experimental and Theoretical Investigation of the Observed Stereoselectivity". J. Org. Chem. 2008, 73, 7921-7927 .

53  Nemykin, V. N.; Galloni, P.; Floris, B.; Barrett, C. D.; Hadt, R. G.; Subbotin, R. I.; Marrani, A. G.; Zanoni, R.; Loim, N. M. " Metal-free and transition-metal tetraferrocenylporphyrins part 1: synthesis, characterization, electronic structure, and conformational flexibility of neutral compounds". Dalton Trans. 2008, 4233-4246 .

54  Herber, R. H.; Nowik, I. Grosland, J. O.; Hadt, R. G..; Nemykin, V. N. " Metal atom dynamics in organometallics: Cyano ferrocenes". J. Organomet. Chem. 2008, 693, 1850-1856.

55  Sengar, R. S.; Nemykin, V. N., Basu, P. "Synthesis, Electrochemistry, Geometric and Electronic Structure of Oxo-Molybdenum Compounds Involved in an Oxygen Atom Transferring System". J. Inorg. Biochem. 2008, 102, 748-756.

56  Robin, B.; Buell, G.; Kiprof, P.; Nemykin, V. N."3H-1,2-Benzoxaborole-1-spiro-4'-(5-oxa-3a-aza-4-borapyrene)". Acta Cryst. 2008, E64, o314-o315, o314/1-o314/8.

57  Pedziwiatr, M.; Kosareff, N. M.; Muller, G.; Koposov, A. Y.; Nemykin, V. N.; Riehl, J. P.; Legendziewicz, J. "Preparation, characterization, and circularly polarized luminiscence of lanthanum and europuim 1,1'-binaphthyl-2,2'-diyl phosphate complexes". J. Alloys Comp. 2008, 451, 251-253.

58  Koposov, A. Y.; Nemykin, V. N.; Zhdankin, V. V. "( S )-Methyl 2-(2-iodobenzamido)-propionate". Acta Cryst. 2007, E63, o4461.

59  Nemykin, V. N.; Hadt, R. G.; Belosludov, R. V.; Mizuseki, H.; Kawazoe, Y. "Influence of Molecular Geometry, Exchange-Correlation Functional, and Solvent Effects in the Modeling of Vertical Excitation Energies in Phthalocyanines Using TDDFT and PCM-TDDFT Methods: Can Modern Computational Chemistry Methods Explain Experimental Controversies?" J. Phys. Chem. A 2007, 111, 12901-12913.

60  Nemykin, V. N.; Makarova, E. A.; Grosland, J. O.; Hadt, R. G.; Koposov, A. Y. "Preparation, Characterization, Molecular and Electronic Structures, TDDFT, and TDDFT/PCM Study of the Solvatochromism in Cyanovinylferrocenes". Inorg. Chem. 2007, 46, 9591-9601.

61  Koposov, A. Y.; Netzel, B. C.; Yusubov M. S; Nemykin, V. N.; Nazarenko, A. Y.; Zhdankin, V. V. "Preparation and structure of oligomeric iodosylbenzene sulfate (PhIO) 3 . SO 3 : stable and water-soluble analog of iodosylbenzene". Eur. J. Org. Chem. 2007, 4475-4478.

62  Stevens, C. V.; Van Meenen, E.; Masschelein, K. G. R.; Eeckhout, Y.; Hooghe, W.; D'Hondt, B.; Nemykin, V. N.; Zhdankin, V. V. "A copper-catalyzed domino radical cyclization route to benzospiro-indolizidinepyrrolidinones". Tetr. Lett. 2007, 48, 7108-7111.

63  Nemykin, V. N.; Barrett, C. D.; Hadt, R. G.; Subbotin, R. I.; Maximov, A. Y.; Polshin, E. V.; Koposov, A. Y. "Mixed-valence states formation in conformationally flexible metal-free 5,10,15,20-tetraferrocenylporphyrin and 5,10-bisferrocenyl-15,20-bisphenylporphyrin". Dalton Trans. 2007, 3378-3389.

64  Nemykin, V. N.; Koposov, A. Y.; Subbotin, R. I.; Sharma, S. "Preparation and characterization of first optically active rigid phthalocyanine dimers". Tetr. Lett. 2007, 48, 5425-5428.

65  Nemykin, V. N.; Maximov, A. Y.; Koposov, A. Y. "Mercury-Free Preparation, Characterization, and Molecular Structure of Tricyanovinylferrocene Using an Unusual Reaction between Ferrocene and Tetracyanoethylene". Organometallics 2007, 26, 3138-3148.

66  Nemykin, V. N.; Polshyna, A. E.; Borisenkova, S. A.; Strelko, V. V. "Preparation, characterization, and catalytic activity of synthetic carbon-supported (phthalocyaninato)cobalt-containing complexes in dodecane-1-thiol oxidation reaction". J. Mol. Cat. A: Chemical 2007, 264, 103-109.

67  Nemykin, V. N.; Olsen, J. G.; Perera, E.; Basu, P. "Synthesis, Molecular and Electronic Structure, and TDDFT and TDDFT-PCM Study of the Solvatochromic Properties of (Me 2 Pipdt)Mo(CO) 4 Complex (Me 2 Pipdt = N,N'-Dimethylpiperazine-2,3-dithione)". Inorg. Chem. 2006, 45, 3557 - 3568.

68  Dieltiens, N.; Claeys, D. D.; Zhdankin, V. V.; Nemykin, V. N.; Allaert, B.; Verpoort, F.; Stevens, C. V. "The pyroglutamate hydantoin rearrangement". Eur. J. Org. Chem. 2006, 2649 – 2660.

69  Nemykin, V. N.; Hadt, R. G. "Influence of Hartree-Fock Exchange on the Calculated Moessbauer Isomer Shifts and Quadrupole Splittings in Ferrocene Derivatives Using Density Functional Theory". Inorg. Chem. 2006, 45, 8297 - 8307.

70  Koposov, A. Y.; Karimov, R. R.; Geraskin, I. M.; Nemykin, V. N.; Zhdankin, V. V. "2-Iodylphenol Ethers: Preparation, X-ray Crystal Structure, and Reactivity of New Hypervalent Iodine(V) Oxidizing Reagents". J. Org. Chem. 2006, 71, 8452 - 8458.

71  Nemykin, V. N.; Maximov, A. Y.; Barrett, C.; Koposov, A. Y.; McGinn, M.; Loim, N. M.; Breggren, T."Synthesis, spectroscopy, and theoretical modeling of mixed-valence states in polyferrocenyl-containing porphyrins and tetraazaporphyrins". J. Porph. Phthalocyan. 2006, 10, 490.

72  Nemykin, V. N.; Belosludov, R. V.; Mizuseki, H.; Kawazoe, Y. "Modeling of the vertical excitation energies in the structural isomers of pyridinoporphyrazines and their structural analogues using TDDFT, PCM-TDDFT, ZINDO/S, and PM3 methods". J. Porph. Phthalocyan. 2006, 10, 792.

73  Nemykin, V. N.; Addei-Maanu, C.; Koposov, A. Y.; Tretyakova, I. N.; Polshyn, E. V. "An investigation of the catalytic degradation of the soluble m -(oxo)dimeric iron phthalocyanine in non-coordinating solvents: spectroscopic and theoretical evidence for the formation of Fe IV -O-Fe IV core". J. Porph. Phthalocyan. 2006, 10, 793.

74  Ladziata, U.; Koposov, A. Y.; Lo, K. Y.; Willing, J.; Nemykin, V. N.; Zhdankin, V. V. "Synthesis, Structure, and Chemoselective Reactivity of N-(2-Iodylphenyl)acylamides: Hypervalent Iodine Reagents Bearing a Pseudo Six-Membered Ring Scaffold". Angew. Chem. Int. Ed. 2005, 44, 7127 -7131.

75  Nemykin, V. N.; McGinn, M.; Koposov, A. Y.; Tretyakova, I. N.; Polshin, E. V.; Loim, N. M.; Abramova, N. V. "Accessing of the Mixed-Valence States in the Zinc Meso-Ferrocenylporphyrin: Experimental and Theoretical Data". Ukr. Khim. Zh. 2005, 69, 79 – 85.

76  McNaughton, R. L.; Mondal, S.; Nemykin, V. N.; Basu, P.; Kirk, M. L. "Oxomolybdenum Tetrathiolates with Sterically Encumbering Ligands: Modeling the Effect of a Protein Matrix on Electronic Structure and Reduction Potentials". Inorg. Chem. 2005, 44, 8216-8222.

77  Nemykin, V. N.; Basu, P. "Oxygen Atom Transfer Reactivity from a Dioxo-Mo(VI) Complex to Tertiary Phosphines: Synthesis, Characterization, and Structure of Phosphoryl Intermediate Complexes". Inorg. Chem. 2005, 44, 7494-7502.

78  Koposov, A. Y.; Nemykin, V. N.; Zhdankin, V. V. "Intra- and intermolecular interactions in the solid state structure of 2-iodylbenzenesulfonamides: a heptacoordinated organic iodine(v) compound". New J. Chem. 2005, 29, 998-1000.

79  Millar, A. J.; Doonan, C. J.; Smith, P. D.; Nemykin, V. N.; Basu, P.; Young, C. G. "Oxygen atom transfer in models for molybdenum enzymes: Isolation and structural, spectroscopic, and computational studies of intermediates in oxygen atom transfer from molybdenum(VI) to phosphorus(III)". Chem. Eur. J. 2005, 11, 3255-3267.

80  Nazarenko, A. Y.; Nemykin, V. N. "Pentaaquadisodium bis(triphenylcyanoborate) (caesignost)". Acta Cryst. 2005, E61, m2317-m2319.

81  Nemykin, V. N.; Basu, P. "Energy-Dependent Electrospray Ionization Mass Spectrometric Studies of Mononuclear Metal Carbonyls". Inorg. Chim. Acta 2005, 358, 2876-2882.

82  Nemykin, V. N.; Laskin, J.; Basu, P. "Isolation, Characterization of an Intermediate in an Oxygen Atom-Transfer Reaction, and the Determination of the Bond Dissociation Energy". J. Am. Chem. Soc. 2004, 126, 8604-8605.

83  Nemykin, V. N. ; Basu, P. " A bifurcated pathway of oxygen atom transfer reactions from a monooxo molybdenum(VI) complex under electrospray ionization mass spectrometric conditions". Dalton Transactions 2004, 1928-193 .

Research papers prior the faculty position at UMD

84  Basu, P.; Nemykin, V. N.; Sengar, R. "Synthesis, spectroscopy, and redox chemistry of encapsulated oxo-Mo(V) centers: implications for pyranopterin-containing molybdoenzymes". Inorg. Chem. 2003, 42, 7489-7501.

85  Carrano, C. J.; Chohan, B. S.; Hammes, B. S.; Kail, B. W.; Nemykin, V. N.; Basu, P."Donor Atom Dependent Geometric Isomers in Mononuclear Oxo-Molybdenum(V) Complexes: Implications for Coordinated Endogenous Ligation in Molybdoenzymes". Inorg. Chem. 2003, 42, 5999-6007.

86  Nemykin, V. N.; Basu, P. "A Comparative Theoretical Investigation of the Vertical Excitation Energies and the Electronic Structure of [Mo V OCl 4 ] - : Influence of Basis Set and Geometry". Inorg. Chem. 2003, 42, 4046-4056 .

87  Sengar, R. S.; Nemykin, V. N.; Basu, P. "Electronic Properties of para -Substituted Thiophenols and Disulfides from 13 C NMR Spectroscopy and ab initio Calculations: Relations to the Hammett Parameters and Atomic Charges". New J. Chem. 2003, 27, 1115-1123 .

88  Mytsyk, V. M.; Nemykin, V. N.; Volkov, S. V. "Synthesis of platinum-containing octacarboxylato(phthalocyaninato)zinc". Ukr. Khim. Zh. 2003, 69, 3-8.

89  Nemykin, V. N.; Davie, S. R.; Mondal, S.; Rubie, N.; Kirk, M. L.; Somogyi, A.; Basu, P. "An Analogue System Displaying All the Important Processes of the Catalytic Cycles Involving Monooxomolybdenum(VI) and Desoxomolybdenum(IV) Centers". J. Am. Chem. Soc. 2002, 124, 756-757.

90  Kail, B.; Nemykin, V. N.; Davie, S. R.; Carrano, C. J.; Hammes, B.; Basu, P. "Synthesis, Characterization, Electrochemistry, Electronic Structure, and Isomerization of Mononuclear Oxo-Molybdenum(V) Complexes: The Serine Gate Hypothesis in the Function of DMSO Reductases". Inorg. Chem. 2002, 41, 1281-1291.

91  Kobayashi, N.; Miwa, H.; Nemykin, V. N. "Adjacent versus Opposite Type Di-Aromatic Ring-Fused Phthalocyanine Derivatives: Synthesis, Spectroscopy, Electrochemistry, and Molecular Orbital Calculations". J. Am. Chem. Soc. 2002, 124, 8007-8020.

92  Kobayashi, N.; Inagaki, S.; Nemykin, V. N.; Nonomura, T. "A novel hemiporphyrazine comprising three isoindolediimine and three thiadiazole units". Angew. Chem., Int. Ed. 2001, 40, 2710-2712.

93  Nemykin, V. N.; Kobayashi, N.; Chernii, V. Y.; Belsky, V. K. "Mössbauer, crystallographic, and density functional theoretical investigation of the electronic structure of bis-ligated low-spin iron (II) phthalocyanines". Eur. J. Inorg. Chem. 2001, 733-743.

94  Kobayashi, N.; Muranaka, A.; Nemykin, V. N. "The first phthalocyanine-based dimer formed by two pyridine-Pd-pyridine bridges". Tetrahedron Lett. 2001, 42, 913-915.

95  Nemykin, V. N.; Kobayashi, N. "A tetraazaporphyrin with an intense, broad near-IR band". Chem. Commun. 2001, 165-166.

96  Volkov, S. V.; Mytsyk, V. M.; Nemykin, V. N. "Method for production of phthalocyanine and its complexes". UKR 07 D487/22, C07F19/00 Patent written in Ukrainian. 2001.

97  Nemykin, V. N.; Polshina, A. E.; Kobayashi, N. "Diels-alder reaction of tribenzo[b,g,l]thiopheno[3,4-q]porphyrazine as a new path for porphyrazine core modification". Chem. Lett. 2000, 1236-1237.

98  Nemykin, V. N.; Myshchyk, V. M. "Synthesis of novel heteronuclear phthalocyanine complexes of zinc and platinum-photosensitizers of "third generation". Ukr. Khim. Zh. (Russ. Ed.) 2000, 66, 67-70.

99  Nemykin, V. N.; Mytsyk, V. M.; Volkov, S. V.; Kobayashi, N. "Synthesis and spectroscopic properties of new phthalocyanine complexes with potentially combined photodynamic activity and cytotoxicity for photodynamic therapy". J. Porphyrins Phthalocyanines 2000, 4, 551-554.

100  Nemykin, V. N.; Tret'yakova, I. N.; Volkov, S. V.; Li, V. D.; Mekhryakova, N. G.; Kaliya, O. L.; Luk'yanets, E. A. "Synthesis, structure and properties of coordination compounds of iron phthalocyanines and their analogues". Russ. Chem. Rev. 2000, 69, 325-346.

101  Nemykin, V. N.; Volkov, S. V. "Mixed-ligand complexes of lanthanides with phthalocyanine and its analogues: synthesis, structure, and spectroscopic properties". Russ. J. Coord. Chem. 2000, 26, 436-450.

102  Nemykin, V. N.; Kobayashi, N.; Mytsyk, V. M.; Volkov, S. V. "The solid phase, room-temperature synthesis of metal-free and metallophthalocyanines, particularly of 2,3,9,10,16,17,23,24-octacyanophthalocyanines". Chem. Lett. 2000, 546-547.

103  Nemykin, V. N.; Polshina, A. E.; Polshin, E. V.; Kobayashi, N. "First direct calculation of the partial quadrupole splitting of ligands for the prediction of Mössbauer spectra parameters in low-spin iron (II) complexes". Mendeleev Commun. 2000, 54-56.

104  Nemykin, V. N.; Polshina, A. E.; Chernii, V. Y.; Polshin, E. V.; Kobayashi, N. "Synthesis, properties and Mössbauer spectra of bisaxially co-ordinated iron(II) phthalocyanine low-spin complexes: the first semi-quantitative explanation of the influence of the character of axial ligands on the spectral parameters". Dalton 2000, 1019-1025.

105  Nemykin, V. N.; Kobayashi, N.; Nonomura, T.; Luk'yanets, E. A. "Low symmetrical phthalocyanines having spectroscopic and electrochemical properties characteristic of unexpected accidental S1 state degeneracy and non-planar distortions". Chem. Lett. 2000, 184-185.

106  Rozhkova, E. A.; Evstigneeva, R. P.; Nemykin, V. N. "Solution coordination chemistry of protohemin IX peptide derivatives". J. Porphyrins Phthalocyanines 1999, 3, 691-702.

107  Nemykin, V. N.; Polshina, A. E.; Chernii, V. Y.; Tretyakova, I. N.; Polshin, E. V.; Kobayashi, N. "Method of calculation of the quadrupole splitting in Mössbauer spectra of axially coordinated iron(II) phthalocyanine complexes". Ukr. Khim. Zh. (Russ. Ed.) 1999, 65, 103-108.

108  Nemykin, V. N.; Mironyuk, T. I.; Zub, V. Ya.; Volkov, S. V. "Chemochromic properties of mixed-ligand lanthanide phthalocyanine complexes with phthalocyanine cation-radical". Ukr. Khim. Zh. (Russ. Ed.) 1998, 64, 75-79.

109  Nemykin, V. N.; Chernii, V. Ya.; Volkov, S. V.; Bundina, N. I.; Kaliya, O. L.; Li, V. D.; Lukyanets, E. A. "Further studies on the oxidation state of iron in m -oxo dimeric phthalocyanine complexes". J. Porphyrins Phthalocyanines 1999, 3, 87-98.

110  Kondratenko, N. V.; Tretyakova, I. N.; Luk'yanets, E. A.; Volkov, S. V.; Orlova, R. K.; Nemykin, V. N.; Yagupolskii, L. M. "Synthesis and characterization of polyfluoroalkoxysulfonyl phthalonitriles and corresponding zinc and cobalt phthalocyanines". Dyes Pigments 1999, 41, 101-109.

111  Nemykin, V. N.; Chernii, V. Ya.; Pol'shin, E. V.; Kostromina, N. A.; Volkov, S. V. "Electronic and Mössbauer spectra of biaxial complexes of iron (II) phthalocyanine with aliphatic and alicyclic amines". Ukr. Khim. Zh. (Russ. Ed.) 1997, 63, 75-84.

112  Nemykin, V. N.; Chernii, V. Ya.; Trachevskii, V. V.; Volkov, S. V. "Proton NMR study of complexation of iron (II) phthalocyanine with aliphatic amines in solutions". Ukr. Khim. Zh. (Russ. Ed.) 1997, 63, 3-6.

113  Nemykin, V. N.; Chernii, V. Y.; Volkov, S. V. "Synthesis and characterization of new mixed-ligand lanthanide-phthalocyanine cation radical complexes". J. Chem. Soc., Dalton Trans. 1998, 2995-3000.

114  Kondratenko, N. V.; Nemykin, V. N.; Lukyanets, E. A.; Kostromina, N. A.; Volkov, S. V.; Yagupolskii, L. M. "The synthesis and properties of some polyfluoroalkoxy substituted phthalocyanines". J. Porphyrins Phthalocyanines 1997, 1, 341-347.

115  Nemykin, V. N.; Kostromina, N. A.; Volkov, S. V. "Synthesis and spectroscopic characteristics of some mixed-ligand octaphenyltetraazaporphyrin lutetium complexes". Ukr. Khim. Zh. (Russ. Ed.) 1997, 63, 3-6.

116  Evstigneeva, R. P.; Rozhkova, E. A.; Nemykin, V. N.; Voronov, S. A.; Zheltukhina, G. A. "Nonplanar distortion modes for C-aminoacyl derivatives of protohemin IX". Dokl. Akad. Nauk 1997, 356, 642-644.

117  Nemykin, V. N.; Voloshin, Y. Z.; Subbotin, N. B. "Method for production of phthalocyanine and its complexes". RU 2061696 C1 19960610 Patent written in Russian. 1996 .

118  Nemykin, V. N.; Subbotin, N. B.; Kostromina, N. A.; Volkov, S. V. "Synthesis and properties of some rare earth 1,2-naphthalocyanines". Ukr. Khim. Zh. (Russ. Ed.) 1995, 61, 3-7.

119  Nemykin, V. N.; Tsivadze, A. Yu.; Subbotin, N. B.; Kostromina, N. A.; Volkov, S. V. "Synthesis and spectra of the mixed-ligand monophthalocyanine complexes of rare-earth elements with bidentate oxygen-containing ligands". Russ. J. Coord. Chem. (Transl. of Koord. Khim.) 1996, 22, 297-302.

120  Nemykin, V. N.; Kostromina, N. A.; Subbotin, N. B.; Volkov, S. V. "Synthesis and physicochemical properties of highly soluble lanthanide tetra-tert-butyl-2,3-naphthalocyanine complexes". Izv. Akad. Nauk, Ser. Khim. 1996, 99-102.

121  Nemykin, V. N.; Kostromina, N. A.; Volkov, S. V. "Synthesis and study of chemichromic properties of high-soluble dysprosium bis(tetra-tert-butylnaphthalocyaninate)". Izv. Akad. Nauk, Ser. Khim. 1995, 1963-1965.

122  Kostromina, N. A.; Chernii, V. Ya.; Nemykin, V. N.; Komarov, I. V. "Complex compounds of phthalocyanineiron(II) with amines". Zh. Neorg. Khim. 1995, 40, 1491-1495.

123  Nemykin, V. N.; Subbotin, N. B.; Kostromina, N. A.; Volkov, S. V.; Luk'yanets, E. A. "Synthesis and properties of asymmetrical dinaphthodibenzoporphyrazine complexes with D 2h symmetry of the ligand". Zh. Neorg. Khim. 1995, 40, 1183-1188.

124  Nemykin, V. N.; Kostromina, N. A.; Volkov, S. V. "Synthesis of lutetium octaalkylthiotetraazaporphyrins". Izv. Akad. Nauk, Ser. Khim. 1995, 572-573.

125  Nemykin, V. N.; Subbotin, N. B.; Kostromina, N. A.; Volkov, S. V. "New, non-symmetrical 2:2 phthalocyanines. 1,2,3,4,15,16,17,18-Octaphenyl-9-23(24)-dinitrophthalo- and 1,2,3,4,19,20,21,22-octaphenyldiphthalo-11,29(30)-di-tert-butyldinaphthalocyanine copper complexes". Mendeleev Commun. 1995, 71-72.

126  Komarov, I. V.; Nemykin, V. N.; Subbotin, N. B. "New selective shift reagents for primary aliphatic amines on the basis of monophthalocyanine lanthanide complexes". Appl. Magn. Reson. 1993, 4, 377-382.

127  Subbotin, N. B.; Nemykin, V. N.; Voloshin, Y. Z. "A synthesis of novel non-symmetrical phthalocyanines". Mendeleev Commun. 1993, 121-122.

128  Brusilovets, A. I.; Rusanov, E. B.; Nemykin, V. N. "Reaction of titanium alkoxides with the N,N-bis(trimethylsilyl)amide-N'-tert-butylimide of thiophosphonic acid". Zh. Obshch. Khim. 1989, 59, 1893-1894.

 

ABSTRACTS OF MAJOR PRESENTATIONS

1  Nemykin, V.; Solntsev, P.; Sabin, J.; Spurgin, K. “Metallocenyl-containing porphyrins, tetraazaporphrins and subphthalocyanines for photoinduced electron-transfer and molecular electronics”. 7 th International Conference on Porphyrins and Phthalocyanines, July 1 – 6, Jeju island, Korea, 2012 , S-09-4.

2  Galloni, P.; Vecchi, A.; Coletti, A.; Floris, B.; Conte, V.; Venanzi, M.; Gatto, E.; Tiravia, M.; Nemykin, V. “Tetraferrocenylporphyrins on surface: Switchable sensitive materials for photoelectrochemical applications”. 7 th International Conference on Porphyrins and Phthalocyanines, July 1 – 6, Jeju island, Korea, 2012 , S09-3.

3  Vecchi, A.; Galloni, P.; Floris, B.; Conte, V.; Nemykin, V. “Study of the interactions between tetraferrocenylporphyrinsand aromatic compounds in solution and on surface”. 7 th International Conference on Porphyrins and Phthalocyanines, July 1 – 6, Jeju island, Korea, 2012 , S09-044.

4  Goetsch, W. R.; Solntsev, P. V.; Sabin, J. R.; Nemykin, V. N. “Unexpected formation of mercury-containing organometallic intermediate in a palladium catalyzed reaction”. Abstracts of Papers, 243rd ACS National Meeting & Exposition, San Diego, CA, United States, March 25-March 29, 2012 , INOR-394.

5  Spurgin, K. L.; Solntsev, P. V.; Sabin, J. R.; Nemykin, V. N. “Syntheses and characterization of the axial ferrocenyl substituted subphthalocyanies”. Abstracts of Papers, 243rd ACS National Meeting & Exposition, San Diego, CA, United States, March 25-March 29, 2012 , INOR-395.

6  Anderson, D. R.; Solntsev, P. V.; Nemykin, V. N.; Gerasimchuk, N. N. “Ferrocene containing metal-organic hybrids - new approach towards synthesis of multi-redox systems”. Abstracts of Papers, 243rd ACS National Meeting & Exposition, San Diego, CA, United States, March 25-March 29, 2012 , INOR-406.

7  Nemykin, V. N.; Solntsev, P. V.; Galloni, P.; Floris, B. “Organometallic Porphyrins and Tetraazaporphyrins with Redox-Controlled Optical and Fluorescent Properties”. 6th International Symposium on Macrocyclic & Supramolecular Chemistry, Brighton, UK July 3-7, 2011 .

8  Nemykin, V. N. “Synthesis and properties of ferrocenyl-containing porphyrins and tetraazaporphyrins”. XI International conference on physical and coordination chemistry of porphyrins and their analogues (ICPC-11). Odessa, Ukraine, July 10-14, 2011 .

9  Yoshimura, A.; Banek, C. T.; Nemykin, V. N.; Yusubov, M. S.; Zhdankin, V. V. “Preparation, X-ray structure and reactions of new recyclable hypervalent iodine(V) reagents based on 2-iodopyridine”. Abstracts of Papers, 241st ACS National Meeting & Exposition, Anaheim, CA, United States, March 27-31, 2011 , ORGN-243.

10  Maskaev, A. V.; Geraskina, M. R.; Galaktionova, A. S.; Yusubov, M. S.; Nemykin, V. N.; Zhdankin, V. V. “Preparation, X-ray structure, and reactivity of potassium 4-iodylbenzenesulfonate: New water-soluble hypervalent iodine reagent”. Abstracts of Papers, 241st ACS National Meeting & Exposition, Anaheim, CA, United States, March 27-31, 2011 , ORGN-200.

11  Dammer, S. J.; Solntsev, P. V.; Nemykin, V. N. “Indium ferrocenyl-containing porphyrins”. Abstracts of Papers, 241st ACS National Meeting & Exposition, Anaheim, CA, United States, March 27-31, 2011 , INOR-618.

12  Solntsev, P.; Nemykin, V.; Gerasimchuk, N. “Synthesis, characterization, mixed-valence properties and photochemistry of axially s-bonded ferrocenyl-containing porphyrines”. Abstracts of Papers, 241st ACS National Meeting & Exposition, Anaheim, CA, United States, March 27-31, 2011 , INOR-611.

13  Nemykin, V. N.; Rohde, G. T.; Sabin, J.; Hadt, R. G.; Solntsev, P.; Grosland, J. O.; Dudkin, S. V.; Makarova, E. A.; Galloni, P.; Floris, B. “On” and “Off” Switchable Multichromophoric Porphyrins Tetraazaporphyrins, and Subphthalocyanines with Organometallic Substituents”. Abstracts of Papers, 6 th International Conference on Porphyrins and Phthalocyanines, Santa Ana Pueblo, NM, USA, July 4 – 9, 2010 .

14  Neu, H. M.; Yoshimura, A.; Rohde, G. T.; Geraskin, I. M.; Zhdankin, V. V.; Nemykin, V. N. “Catalytic oxidation of organic substrates using iron(III) porphyrins and phthalocyanines as catalysts and hypervalent iodine(III) and iodine(V) compounds as oxidants”. Abstracts of Papers, 6 th International Conference on Porphyrins and Phthalocyanines, Santa Ana Pueblo, NM, USA, July 4 – 9, 2010 .

15  Neu, H. M.; Yoshimura, A.; Zhdankin, V. V.; Nemykin, V. N. “Catalytic activity of symmetric and asymmetric iron(III) µ-oxo phthalocyanine dimers and water soluble iron porphyrins”. Abstracts of Papers, 239th ACS National Meeting, San Francisco, CA, United States, March 21-25, 2010 , INOR-925.

16  Dahlby, M. R.; Muriithi, J. T.; Rohde, G. T.; Nemykin, V. N. “Ion-sensing properties of ferrocenyl-diaminomaleonitrile derivatives”. Abstracts of Papers, 239th ACS National Meeting, San Francisco, CA, United States, March 21-25, 2010 , INOR-303.

17  Nemykin, V. N., Rohde, G. T.; Barrett, C.; Grossland, J. O.; Galloni, P.; Floris, B.; Zanoni, R.; Herber, R. H. “Targeting of the mixed-valence states in polyferrocene-containing porphyrins and tetraazaporphyrins”. Abstracts of Papers, 2 nd Georgian Bay International Conference on Bioinorganic Chemistry, Parry Sound , Ontario , Canada , May 26-29, 2009 , S 1-2, p22.

18  Rohde, G. T.; Hadt, R. G.; Nemykin, V. N. “Formation, stability aggregation properties and the electronic structure of soluble zinc tetra-tert-butylphthalocyanine cation-radicals”. Abstracts of Papers, 2 nd Georgian Bay International Conference on Bioinorganic Chemistry, Parry Sound , Ontario , Canada , May 26-29, 2009 , P 43, p55.

19  Neu, H. M.; Rohde, G. T.; Geraskin, I. M.; Zhdankin, V. V.; Nemykin, V. N. “The preparation and catalytic activity of symmetrical, unsymmetrical and chiral iron m -oxo phthalocyanine dimmers”. 2 nd Georgian Bay International Conference on Bioinorganic Chemistry, Parry Sound , Ontario , Canada , May 26-29, 2009 , P 32, p52.

20  Rohde, G. T.; Nemykin, V. N.; Floris, B.; Reina, G.; Herber, R. H.; Nowik, I. Accessing of the multiple mixed-valence states in tetraferrocenyl-porphyrins”. Abstracts of Papers, 237th ACS National Meeting, Salt Lake City , UT , United States , March 22-26, 2009 , INOR-164.

21  Neu, H. M.; Geraskin, I. M.; Zhdankin, V. V.; Nemykin, V. N. “ The preparation and catalytic activity of the phthalocyanine iron m -oxo dimers”. Abstracts of Papers, 237th ACS National Meeting, Salt Lake City , UT , United States , March 22-26, 2009 , INOR-715.

22  Geraskin, I. M.; Pavlova, O.; Nemykin, V. N.; Zhdankin, V. V. “Hypervalent iodine compounds as oxidants in phthalocyanine catalyzed oxidations of anthracene”. Abstracts of Papers, 237th ACS National Meeting, Salt Lake City , UT , United States , March 22-26, 2009 , ORGN-573.

23  Geraskin, I. M.; Subbotin, R. I.; Nemykin, V. N.; Zhdankin, V. V. “Organic iodine(V) compounds as terminal oxidants in phthalocyanine catalyzed oxidations of alcohols” Abstracts of Papers, 5 th International Conference on Porphyrins and Phthalocyanines, Moscow, Russia, July 6-11, 2008 , 630 .

24  Nemykin, V. N.; Barrett, C.; Hadt, R. G.; Rohde, G. T.; Grossland, J. O.; Galloni, P.; Bizzari, C.; Floris, B.; Loim, N. M. “Polyferrocenyl-contained porphyrins and tetraazaporphyrins: synthesis, redox properties, and electronic structure”. Abstracts of Papers, 5 th International Conference on Porphyrins and Phthalocyanines, Moscow , Russia , July 6-11, 2008 , 151.

25  Subbotin, R.; Jones, J. A.; Nemykin, V. N. Catalytic activity of the soluble transition-metal phthalocyanine dimers in oxidation reactions”. Abstracts of Papers, 235th ACS National Meeting, New Orleans, LA, United States, April 6-10, 2008 INOR-255.

26  Hadt, R. G.; Nemykin, V. N. “ Theoretical modeling of Mossbauer, EPR, and UV-Vis spectroscopic parameters in neutral, mixed-valence, and doubly oxidized biferrocenes using density functional theory (DFT) and time dependent DFT”. Abstracts of Papers, 235th ACS National Meeting, New Orleans, LA, United States, April 6-10, 2008 , INOR-294.

27  Rohde, G. T.; Hadt, R. G.; Nemykin, V. N. “ Combined UV-Vis, MCD, DFT, TDDFT, and PCM-TDDFT study on oxidized zinc phthalocyanine monomer and dimer species”. Abstracts of Papers, 235th ACS National Meeting, New Orleans , LA , United States , April 6-10, 2008 , INOR-716.

28  Kazhkenov, Z. M.; Karimov, R. R.; Nemykin, V. N.; Zhdankin, V. V. “ Preparation and structure of N,N-disubstituted 2-iodylaniline oxides: New pseudocyclic iodine(V) oxidants”. Abstracts of Papers, 235th ACS National Meeting, New Orleans , LA , United States , April 6-10, 2008 , ORGN-084.

29  Geraskin, I. M.; Subbotin, R.; Nemykin, V. N.; Zhdankin, V. V. “ Organic iodine(V) compounds as terminal oxidants in phthalocyanine catalyzed oxidations of alcohols”. Abstracts of Papers, 235th ACS National Meeting, New Orleans , LA , United States , April 6-10, 2008 , ORGN-182

30  Nemykin, V. N.; Subbotin, R.; Sharma, S.; Koposov, A. Y. “Preparation, characterization, asymmetric catalysis, and molecular recognition of chiral substrates with enantiomerically pure phthalocyanine dimers”. Abstracts of Papers, 233rd ACS National Meeting, Chicago, IL, United States, March 25-29, 2007 , INOR-224.

31  Nemykin, V. N.; Hadt, R.; Belosludov, R. “DFT modeling of Mossbauer spectra parameters and absorption properties in organometallic and macrocyclic compounds”. Abstracts of Papers, 233rd ACS National Meeting, Chicago, IL, United States, March 25-29, 2007 , INOR-1067.

32  Nemykin, V. N.; Maximov, A. Y.; Barrett, C.; Koposov, A. Y.; McGinn, M.; Loim, N. M.; Breggren, T. “Synthesis, spectroscopy, and theoretical modeling of mixed-valence states in polyferrocenyl-containing porphyrins and tetraazaporphyrins”. 4 th International Conference on Porphyrins & Phthalocyanines, Rome, Italy, July 2 – 7, 2006 .

33  Nemykin, V. N.; Belosludov, R. V.; Mizuseki, H.; Kawazoe, Y. “Modeling of the vertical excitation energies in the structural isomers of pyridinoporphyrazines and their structural analogues using TDDFT, PCM-TDDFT, ZINDO/S, and PM3 methods”. 4 th International Conference on Porphyrins & Phthalocyanines, Rome , Italy , July 2 – 7, 2006 .

34  Nemykin, V. N.; Addei-Maanu, C.; Koposov, A. Y.; Tretyakova, I. N.; Polshyn, E. V. “An investigation of the catalytic degradation of the soluble m -(oxo)dimeric iron phthalocyanine in non-coordinating solvents: spectroscopic and theoretical evidence for the formation of Fe IV -O-Fe IV core”. 4 th International Conference on Porphyrins & Phthalocyanines, Rome, Italy, July 2 – 7, 2006 .

35  Pedziwatr, M.; Muller, G.; Nemykin, V. N., Riehl, J. P.; Legendziewicz, J. “Preparation, characterization, circularly polarized luminescence, and theoretical modeling of chiral BINOL-containing lanthanide complexes”. 6 th International Conference on f-Elements, Wroclaw , Poland , September 2 – 7, 2006 .

36  Nemykin, V. N.; McGinn, M.; Koposov, A. Y.; Polshin, E. V.; Loim, N. M.; Kobayashi, N. “Accessing of mixed-valence states in metal-free and transition-metal ferrocenyl porphyrins: Spectroscopy, electrochemistry, and DFT calculations”. Abstracts of Papers, 230th ACS National Meeting, Washington, DC, United States, Aug. 28-Sept. 1, 2005, INOR-485.

37  Nemykin, V. N.; Olsen, J. G.; Basu, P. “Modeling of excited states, solvatochromic, and EPR properties of molybdenum complexes: Methodology and application”. Abstracts of Papers, 230th ACS National Meeting, Washington, DC, United States, Aug. 28-Sept 1, 2005 , INOR-103.

38  Ladziata, U.; Koposov, A. Y.; Lo, K. Y.; Willging, J.; Nemykin, V. N.; Zhdankin, V. V. “Synthesis, structure, and oxidative properties of N-(2-iodyl-phenyl)-acylamides: Novel hypervalent iodine reagents bearing pseudo six-membered ring scaffold”. Abstracts of Papers, 230th ACS National Meeting, Washington , DC , United States , Aug. 28-Sept. 1, 2005 , ORGN-107.

39  Basu, P.; Carrano, C.; Nemykin, V. N.; Kail, B. W. “Serine gate hypothesis in the function DMSO reductases”. Abstracts of Papers, 224th ACS National Meeting, Boston, MA, United States, August 18-22, 2002 , INOR-144.

40  Nemykin, V. N.; Basu, P. “Oxygen atom transfer reactions from discrete monooxo molybdenum(VI) complexes”. Abstracts of Papers, 224th ACS National Meeting, Boston, MA, United States, August 18-22, 2002 , INOR-140.

41  Nemykin, V. N.; Polshin, E. V.; Kobayashi, N. “The theoretical interpretation and prediction of M ö ssbauer spectral parameters in iron phthalocyanine and tetraazaporphyrine complexes: from empirical correlations to density functional investigations”. Abstracts of Papers, First International Conference on Porphyrins and Phthalocyanines, Dijon, France, June 2000 , oral-260.

42  Yuseva, E. I.; Abramova, N. V.; Sokolov, V. I.; Loim, N. M.; Nemykin, V. N.; Peterleitner, M. G.; Tretyakova, I. N.; Polshin, E. V.; Kobayashi, N. “The chemical and electrochemical oxidation of meso-ferrocenylporphyrins”. Abstracts of Papers, First International Conference on Porphyrins and Phthalocyanines, Dijon, France, June 2000 , post-478.

43  Mytsk, V. M.; Nemykin, V. N.; Tretyakova, I. N.; Volkov, S. V. “Synthesis of novel Pt-containing phthalocyanine complexes”. Abstracts of Papers, 4th school of young scientists on chemistry of porphyrins and their analogues, Ivanovo, Russia, August, 2000 , 44-45 (in Rusian).

44  Nemykin, V. N.; Chernii, V. Y.; Polshin, E. V.; Belsky, V. K.; Voloshin, Y. Z.; Volkov, S. V. “Synthesis, UV-VIS, M ö ssbauer and NMR spectra of bis (aliphatic amine) (phthalocyaninato) iron (II) complexes: influence of axial ligands on spectroscopic parameters”. Abstracts of Papers, 2nd International symposium on phthalocyanines, Edinburgh, Scotland, September 1998 , P24.

45  Nemykin, V. N.; Tretiakova, I. N.; Klencsar, Z.; Kuzmann, E.; Subbotin, N. B.; Volkov, S. V.; Lukyanets, E. A. “Sandwich-type and mixed-ligand phthalocyanine lanthanide complexes: different compounds from different starting materials and reaction conditions”. Abstracts of Papers, 2nd International symposium on phthalocyanines, Edinburgh, Scotland, September 1998 , P25.

46  Nemykin, V. N.; Chernii, V. Y.; Volkov, S. V.; Kaliya, O. L.; Lukyanets, E. A. “Discussion about valence state of iron ions in phthalocyanine m -oxo bridged complexes”. Abstracts of Papers, 2nd International symposium on phthalocyanines, Edinburgh, Scotland, September 1998 , P26.

47  Nemykin, V. N.; Stoojin, P. N.; Chernii, V. Y.; Polshin, E. V.; Voloshin, Y. Z. “Synthesis and spectra of an axially substituted iron (II) octaphenyltetraazaporphyrins”. Abstracts of Papers, XXII International symposium on macrocyclic chemistry, Seoul, Korea, August 1997 , 90.

48  Nemykin, V. N.; Chernii, V. Y.; Subbotin, N. B. “Characterization of new chemio- and solvatochromic NIR dyes on the base of mixed-ligand phthalo- and naphthalocyanine lanthanide complexes”. Abstracts of Papers, NOTA workshop, Trest, Czech Republic, September, 1997 , P7.

49  Rozhkova, E. A.; Nemykin, V. N.; Voronov, S. A.; Zheltukhina, G. A.; Evstigneeva, R. P.; Volkov, S. V. “Synthesis and properties of peroxidase active site models”. Abstracts of Papers, International workshop on peroxidase biotechnology and application, St.-Petersburgh, Russia, 1997 .

50  Rozhkova, E. A.; Nemykin, V. N.; Zheltukhina, G. A.; Evstigneeva, R. P.; Volkov, S. V. “Synthesis, electronic, ESR and M ö ssbauer spectroscopy of protohemine IX C-aminoacyl derivatives as hemoproteins models”. Abstracts of Papers, International conference on chemistry of metals in biological systems, Tomar, Portugal, 1997 .

51  Nemykin, V. N.; Volkov, S. V. “Parametrization of an axial nitrogen-containing ligands in the low spin iron (II) phthalocyanines: predicting of the spectroscopic characteristics”. Abstracts of Papers, XII-th conference on Physical methods in coordination and supramolecular chemistry, Chisinau, Moldova, September 1996 , 35.

52  Nemykin, V. N.; Chernii, V. Y.; Kostromina, N. A.; Volkov, S. V. “Synthesis and characterisation of an axially substituted low spin iron(II) octaphenyltetraazaporphyrines”. Abstracts of Papers, XII-th conference on Physical methods in coordination and supramolecular chemistry, Chisinau, Moldovia, September 1996 , 62.

53  Kostromina, N. A.; Nemykin, V. N. “New complexes of phthalocyanines and its analogues: perspective of applications”. Abstracts of Papers, VII International conference on the chemistry of porphyrines and its analogues, S-Peterburg, Russia, June 1995 , 9 (in Russian).

54  Nemykin, V. N.; Lukyanets, E. A.; Subbotin, N. B.; Kostromina, N. A.; Volkov, S. V. “Synthesis and investigation of new non-symmetrical perphenylsubstituted mono- and dibenzotetraazaporphyrines”. Abstracts of Papers, VII International conference on the chemistry of porphyrines and its analogues, S-Peterburg, Russia, June 1995 , 24 (in Russian).

55  Chernii, V. Y.; Nemykin, V. N.; Kostromina, N. A. “Investigation of the selectively of axial coordination of aliphatic amines to iron (II) phthalocyanine”. Abstracts of Papers, First international conference on biocoordination chemistry. Ivanovo , Russia , December 1994 , 100 (in Russian).

56  Nemykin, V. N.; Subbotin, N. B.; Kostromina, N. A.; Volkov, S. V. “Synthesis of new non-symmetrical phthalo- and naphthalocyanines”. Abstracts of Papers, First international conference on biocoordination chemistry. Ivanovo , Russia , December 1994 , 65 (in Russian).

57  Nemykin, V. N.; Kostromina, N. A.; Volkov, S. V. “Synthesis and properties of some mixed ligand high soluble lanthanide (III) 2,3-naphthalocyanines”. Abstracts of Papers, 2-nd International conference on f-elements; Helsinki, Finland, August 1994 , 107.

58  Kalibabchyk, V. A.; Pecheny, A. B.; Samarskii, V. A.; Nemykin, V. N. “Application of complexation process to water purification”. Abstracts of Papers, XV Mendeleev congress on general and applied chemistry, Minsk, Russia, May 1993 , 65 (in Russian).

59  Nemykin, V. N.; Kostromina, N. A.; Volkov, S. V. "Red" phthalocyanines: the synthesis and the properties of the new class of macrocyclic compounds”. Abstracts of Papers, COLORCHEM-96, Pardubice-Rybitvi, Czech Republic, May 1996 , 153.

60  Chernii, V. Y.; Nemykin, V. N.; Kostromina, N. A. “Influence of electronic and steric effects of axial ligands on the spectroscopy of phthalocyaninato iron(II) complexes”. Abstracts of Papers, COLORCHEM-96, Pardubice-Rybitvi, Czech Republic, May 1996 , 154.

61  Nemykin, V. N.; Chernii, V. Y.; Volkov, S. V. "Red" phthalocyanines: a chemiochromic properties of new class of macrocyclic compounds”. Abstracts of Papers, Ukrainian conference on inorganic chemistry, Kiev, Ukraine, September 1996 (in Russian).

62 Chernii, V. Y.; Nemykin, V. N.; Polshin, E. V.; Komarov, I. V.; Kostromina, N. A.; Volkov, S. V. “Electronic, NMR and M ö ssbauer spectra of axially coordinated iron(II) phthalocyanine complexes”. Abstracts of Papers, Ukrainian conference on inorganic chemistry, Kiev, Ukraine, September 1996 (in Russian).

 

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