Waste Minimization
The University of Minnesota is committed to the protection of human
health and the environment. To meet these commitments, the University
strongly encourages its employees to utilize chemical waste
minimization techniques to reduce the volume and toxicity of chemical
wastes produced at the University. An important benefit from
waste minimization is that it will help reduce the University's
escalating chemical disposal costs which are currently estimated at
$1.7 million annually and expected to rise with federal and state
restrictions in the future. These disposal costs come out of research
grants and operating funds. The following sections describe common
waste minimization techniques.
The UMD Office of Environmental Health and Safety, (218)
726-7139, can assist you in your pollution prevention efforts, other
references and technical assistance, case studies, maybe obtained from
the Minnesota Technical Assistance Program (MnTAP) http://www.mntap.umn.edu/
See the University Stores catalog or call Lab Services
at (612) 625-6545 to order these recommended products.
Product Substitution
Substitute nonhazardous or less toxic materials in your
chemical processes and experiments. Some examples are:
| If You Use: |
Substitute: |
| Xylene, benzene and
toluene containing reagents in histology laboratories |
Citric acid
based reagents (e.g. AmeriClear) |
| Standard xylene or
toluene based cocktails in radioactive tracer studies |
Nonhazardous
proprietary liquid scintillation cocktails; call the Radiation
Protection Division at (612) 626-6764 for information. |
| Solvent based inks in
printing operations |
Soy based
inks |
| Formaldehyde in
cleaning hospital kidney dialysis machines |
Peracetic
acid |
| Mercury thermometers |
Non-mercury
thermometers |
| Solvent extraction |
Solid phase
or supercritical fluid extraction |
| Sulfuric acid/
potassium dichromate (chromerge) cleaning solutions |
Detergents
and enzymatic cleaners |
| Ethidium bromide |
New
filtration product to concentrate solvent waste 10 times |
| Phosphate chloride
detergents for lab glass washing |
Non-phosphate,
non-chloride detergents |
Process Modification
To the extent that it does not affect vital research or
teaching, modify experiments to decrease the quantity of hazardous
chemicals used and generated. Micro analysis techniques can greatly
reduce the amount of waste generated. An example of this is the use of
microscale chemistry in entry level teaching laboratories. Also, new
equipment can reduce the amount waste generated. For example, new high
performance liquid chromatography (HPLC) machines use microprocessors
to reduce the amount of waste generated. Contact peers or professional
organizations for the latest pollution prevents techniques.
Maintenance shops or service areas (such as heavy
equipment shops or printing and graphics) should also utilize pollution
prevention techniques. Contact vendors for information on nonhazardous
substitutes.
Segregation and Characterization
- Do not mix wastes. Especially do not
mix hazardous wastes with nonhazardous wastes.
- Accurately label the waste bottles as to their exact
content.
Segregation and characterization allows waste to be
redistributed for reuse if someone else in the University system can
use the chemicals; if the waste cannot be redistributed, segregation
simplifies chemical recycling, such as distillation or reclamation, and
minimizes costs.
Reclamation
The University reclaims some precious metals and
valuable chemicals to reduce waste treatment costs. The following are
examples of wastes you should send to the Chemical Waste Program for
reclamation:
- Acetonitrile and methanol waste from HPLC machines
for distillation,
- Fuel grade solvents and used motor and pump oil for
refining by a vendor for use as fuel,
- Metallic Mercury for redistillation and resale by a
vendor, and
- Photo fixer waste for recovery of silver.
Neutralization and Deactivation
Some laboratories generate a simple, pure chemical
stream, such as a dilute acid or base that can be rendered nonhazardous
by simple neutralization. Other labs may generate a dilute aqueous
stream that contains a metal which can be easily precipitated. In these
cases, labs are encouraged to call the UMD Chemical Waste Program at
7139 to determine if they can process these materials to render them
nonhazardous.
Inventory Management and Control
Audit chemical supplies and use inventory control:
- Survey all the chemicals in your labs, shops and
storerooms and dispose of those chemicals that have not been used
within the past year or two.
- Purchase only the quantity of chemical required for
specific projects.
- If you have chemicals stored in a "shared" storeroom,
take responsibility to redistribute or dispose of those old chemicals
left by personnel or students no longer with the University.
- When purchasing automated equipment, use the type and
amount of hazardous waste generated by the machine as one of the
purchasing criteria.
Training and Awareness
Train your employees when they are first hired and
annually thereafter in waste minimization concepts. Training should
include:
- The concepts described above.
- Annual documentation of the training signed by both
the employee and supervisor.
See New Employee and Annual Update Training
Documentation of Waste Reduction
Efforts
Use the "Record of Pollution Prevention Efforts" form
(see Appendix II) to document reduction in your work area. Each
January, send an updated copy to the address on the form. The
information collected is reported to the State of Minnesota and is also
used as a teaching tool for other University of Minnesota laboratories
and shops.
Chemical Redistribution Program
Many materials treated as chemical waste are actually
surplus chemicals which may be of use to other researchers. To assist
in waste reduction, the Chemical Redistribution Program accepts both
unopened and opened containers of unwanted but still usable chemicals
and labware, and redistributes them to other University laboratories.
This redistribution of chemicals and labware is provided FREE of charge
to any interested University department or research laboratory.
If you wish to participate in this program, but you do
not have a computer link with the University network, the lists and
information about this program can be sent to you.
An effective redistribution program is dependent on a
constant influx of materials. When filling out the waste packing form,
keep in mind that chemicals which are potentially of use to other
researchers should be indicated by checking the column marked
"RECY" so that they may be pulled out of the waste stream and
examined for possible redistribution. Inform the UMD EHSO about
laboratory clean-outs or of any unwanted reagent chemicals, at
726-6764. A member of our staff will come out to your site to
evaluate the chemicals for redistribution.
Note that certain chemicals are particularly desirable
for redistribution and include the following:
| ACIDS |
SOLVENTS |
| Acetic acid (glacial) |
Acetone |
| Hydrochloric acid |
Chloroform |
| Sulfuric acid |
Dichloromethane (methylene chloride) |
| OXIDIZERS |
Ethyl acetate |
| Bromine |
Glycerol |
| Potassium chlorate |
Hexanes |
| Potassium dichromate |
Isopropyl alcohol |
| Silver nitrate |
Methanol |
| POISONS |
Petroleum ether |
| Indicators |
Toluene |
| Iodine (solid or solution) |
Xylenes |
| Metals (powders, dust, shot) |
| Sodium, calcium, silver, and potassium salts |
|