Waste Minimization
The University of Minnesota is
committed to the protection of human health and the environment. To
meet these commitments, the University strongly encourages its
employees to utilize chemical waste minimization techniques to reduce
the volume and toxicity of chemical wastes produced at the
University.
An important benefit from waste minimization is that it will help
reduce the University's escalating chemical disposal costs which are
currently estimated at $1.7 million annually and expected to rise with
federal and state restrictions in the future. These disposal costs come
out of research grants and operating funds. The following sections
describe common waste minimization techniques.
The UMD Office of Environmental Health and Safety, (218)
726-7139, can
assist you in your pollution prevention efforts, other references and
technical assistance, case studies, maybe obtained from the Minnesota
Technical Assistance Program (MnTAP) http://www.mntap.umn.edu/
See the University Stores catalog or call Lab Services
at (612) 625-6545 to order these recommended products.
Product Substitution
Substitute nonhazardous or less toxic materials in your
chemical processes and experiments. Some examples are:
| If You Use: |
Substitute: |
| Xylene, benzene and
toluene containing reagents in histology laboratories |
Citric acid
based reagents (e.g. AmeriClear) |
| Standard xylene or
toluene based cocktails in radioactive tracer studies |
Nonhazardous
proprietary liquid scintillation cocktails; call the Radiation
Protection Division at (612) 626-6764 for information. |
| Solvent based inks in
printing operations |
Soy based
inks |
| Formaldehyde in
cleaning hospital kidney dialysis machines |
Peracetic
acid |
| Mercury thermometers |
Non-mercury
thermometers |
| Solvent extraction |
Solid phase
or supercritical fluid extraction |
| Sulfuric acid/
potassium dichromate (chromerge) cleaning solutions |
Detergents
and enzymatic cleaners |
| Ethidium bromide |
New
filtration product to concentrate solvent waste 10 times |
| Phosphate chloride
detergents for lab glass washing |
Non-phosphate,
non-chloride detergents |
Process Modification
To
the extent that it does not affect vital research or teaching, modify
experiments to decrease the quantity of hazardous chemicals used and
generated. Micro analysis techniques can greatly reduce the amount of
waste generated. An example of this is the use of microscale chemistry
in entry level teaching laboratories. Also, new equipment can reduce
the amount waste generated. For example, new high performance liquid
chromatography (HPLC) machines use microprocessors to reduce the amount
of waste generated. Contact peers or professional organizations for the
latest pollution prevents techniques.
Maintenance shops or
service areas (such as heavy equipment shops or printing and graphics)
should also utilize pollution prevention techniques. Contact vendors
for information on nonhazardous substitutes.
Segregation and Characterization
- Do not mix wastes. Especially do not
mix hazardous wastes with nonhazardous wastes.
- Accurately label the waste bottles as to their exact
content.
Segregation
and characterization allows waste to be redistributed for reuse if
someone else in the University system can use the chemicals; if the
waste cannot be redistributed, segregation simplifies chemical
recycling, such as distillation or reclamation, and minimizes costs.
Reclamation
The
University reclaims some precious metals and valuable chemicals to
reduce waste treatment costs. The following are examples of wastes you
should send to the Chemical Waste Program for reclamation:
- Acetonitrile and methanol waste from HPLC machines
for distillation,
- Fuel grade solvents and used motor and pump oil for
refining by a vendor for use as fuel,
- Metallic Mercury for redistillation and resale by a
vendor, and
- Photo fixer waste for recovery of silver.
Neutralization and Deactivation
Some
laboratories generate a simple, pure chemical stream, such as a dilute
acid or base that can be rendered nonhazardous by simple
neutralization. Other labs may generate a dilute aqueous stream that
contains a metal which can be easily precipitated. In these cases, labs
are encouraged to call the UMD Chemical Waste Program at 7139 to
determine if they can process these materials to render them
nonhazardous.
Inventory Management and Control
Audit chemical supplies and use inventory control:
- Survey
all the chemicals in your labs, shops and storerooms and dispose of
those chemicals that have not been used within the past year or two.
- Purchase only the quantity of chemical required for
specific projects.
- If
you have chemicals stored in a "shared" storeroom, take responsibility
to redistribute or dispose of those old chemicals left by personnel or
students no longer with the University.
- When purchasing
automated equipment, use the type and amount of hazardous waste
generated by the machine as one of the purchasing criteria.
Training and Awareness
Train your employees when they are first hired and
annually thereafter in waste minimization concepts. Training should
include:
- The concepts described above.
- Annual documentation of the training signed by both
the employee and supervisor.
See New Employee and Annual Update Training
Documentation of Waste Reduction
Efforts
Use
the "Record of Pollution Prevention Efforts" form (see Appendix II) to
document reduction in your work area. Each January, send an updated
copy to the address on the form. The information collected is reported
to the State of Minnesota and is also used as a teaching tool for other
University of Minnesota laboratories and shops.
Chemical Redistribution Program
Many
materials treated as chemical waste are actually surplus chemicals
which may be of use to other researchers. To assist in waste reduction,
the Chemical Redistribution Program accepts both unopened and opened
containers of unwanted but still usable chemicals and labware, and
redistributes them to other University laboratories. This
redistribution of chemicals and labware is provided FREE of charge to
any interested University department or research laboratory.
If you wish to participate in this program, but you do
not have a
computer link with the University network, the lists and information
about this program can be sent to you.
An effective
redistribution program is dependent on a constant influx of materials.
When filling out the waste packing form, keep in mind that chemicals
which are potentially of use to other researchers should be indicated
by checking the column marked "RECY"
so that they may be pulled out of the waste stream and examined for
possible redistribution. Inform the UMD EHSO about laboratory
clean-outs or of any unwanted reagent
chemicals, at 726-6764. A member of our staff will come out to
your site to evaluate the chemicals for redistribution.
Note that certain chemicals are particularly desirable
for redistribution and include the following:
| ACIDS |
SOLVENTS |
| Acetic acid (glacial) |
Acetone |
| Hydrochloric acid |
Chloroform |
| Sulfuric acid |
Dichloromethane (methylene chloride) |
| OXIDIZERS |
Ethyl acetate |
| Bromine |
Glycerol |
| Potassium chlorate |
Hexanes |
| Potassium dichromate |
Isopropyl alcohol |
| Silver nitrate |
Methanol |
| POISONS |
Petroleum ether |
| Indicators |
Toluene |
| Iodine (solid or solution) |
Xylenes |
| Metals (powders, dust, shot) |
| Sodium, calcium, silver, and potassium salts |
|