Viktor
V. Zhdankin
Professor
Department
of Chemistry and Biochemistry
1039
University Drive
University
of Minnesota Duluth
Duluth,
Minnesota 55812-3020
Phone:
(218) 726-6902
Fax: (218)
726-7394
E-mail:
vzhdanki@d.umn.edu
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PERSONAL
DATA:
BORN:
1956 in Russia; Naturalized
US Citizen since 1999
ADDRESS:
Department of Chemistry and Biochemistry, 1039 University
Drive, University of
Minnesota Duluth, Duluth, MN 55812
TELEPHONE:
Office - (218) 726-6902; FAX: (218) 726-7394
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EDUCATION:
Doctor of
Science (the highest scientific degree in
Russia): 1987, Department
of Chemistry, Moscow
State
University, Moscow,
Russia
Ph.D. (Russian
analog): 1981, Department
of Chemistry,
Moscow State University,
Moscow, Russia Advisor: Professor
Nikolai S. Zefirov
B.S./M.S.
(Russian analog): 1978, Department of Chemistry,
Moscow State University,
Moscow, Russia
ACADEMIC
EXPERIENCE:
Professor,
Department
of Chemistry, University of
Minnesota Duluth, July
1999 - present.
Director of Graduate
Studies in Chemistry (Chem–Duluth program), University of
Minnesota, 2002 - 2006 and July 2008 to present.
Associate
Professor, Department
of Chemistry, University of
Minnesota Duluth, July
1996 - June 1999.
Assistant Professor, Department
of Chemistry, University of
Minnesota Duluth,
September 1993-June 1996.
Senior Research Associate, Department
of Chemistry, University of Utah
(with Professor
P.J. Stang), January 1990 - August 1993.
Instructor of Organic Chemistry, Department of Chemistry, University of Utah, January 1991 -
August 1993.
Leading Research Fellow - Head of Research
Group, Department of Chemistry, Moscow State University, Moscow,
Russia, October 1989 - December 1992.
Senior Research Fellow, Department of Chemistry,
Moscow State University, Moscow, Russia, October 1988 - October 1989.
Visiting Scientist (IREX exchangee), Department
of Chemistry, University of Minnesota Duluth, December 1987 -
September 1988.
Research Fellow, Department of Chemistry, Moscow
State University, Moscow, U.S.S.R., January
1982 - December 1987.
RESEARCH INTERESTS:
Exploratory
Synthetic Organic Chemistry of
Hypervalent Main-Group Elements:
preparation, identification and uses of new organic derivatives of
iodine(III), xenon(II), selenium(IV), phosphorus(V).
Chemistry of Organoboronic Acids: preparation,
structural investigation and synthetic utilization of
1-hydroxybenzoboroxoles and alkynylboronates.
Synthetic Organic Chemistry of Fluorine:
preparation of perfluoroalkylated compounds; organic reactions of
powerful fluorinating reagents (XeF2,
CsOSO2OF, etc.); synthetic
application of fluoroorganic compounds.
Mechanistic Physical-Organic Chemistry:
generation and chemistry of carbocations and other reactive
intermediates; nucleophilic reactivity; electrophilic addition to
unsaturated compounds.
Chemistry of Acetylenes: preparation and
synthetic application of novel substituted acetylenes.
SIGNIFICANT
PROFESSIONAL SERVICE AND AWARDS
• University of
Minnesota Jean G. Blehart
Distinguished Teaching Award, 2006
•
Chancellor's
Award for Distinguished
Research, 2004
•
Camille
and Henry Dreyfus Scholar,
1997-2000
•
Scientific Editor and a Member of Control Board of ARKIVOC,
Online Journal of Organic Chemistry (http://www.arkat-usa.org/),
April 2003 - present.
•
Member of
Editorial Board; Mendeleev
Communications,
March 1998 - present.
•
Member of
Editorial Board; Russian
Journal
of Organic Chemistry, January 1989 -
January 1993.
•
Member of
Editorial Board; Journal of
the
Mendeleev's Russian Chemical Society, March 1989 -
January 1996.
•
Member of
Panel-2 (Organic Chemistry) of
International
Science Foundation on Long-Term Research Grants (Washington,
DC), December 1993 - January 1995.
•
Member
of Organizing Committee of First International Conference
on Hypervalent
Iodine, Thessaloniki/Halkidiki, Greece, September 2001; Second
International Conference
on Hypervalent
Iodine, Thessaloniki, Greece, May 2006; International
symposium “Advances in
Science for Drug Discovery”, Moscow, 2005.
•
Honorable
Diploma of the Academy of
Sciences
of the U.S.S.R. for Young Scientists, 1985.
•
National Award from
the Government of the U.S.S.R. for a Scientific Discovery "Nucleophilic
Properties of Nucleofugic Anions", 1985.
SELECTED RECENT
PUBLICATIONS (all papers):
Preparation, X-ray Structure, and Oxidative Reactivity of N-(2-Iodylphenyl)tosylamides and
2-Iodylphenyl Tosylate: Iodylarenes Stabilized by Ortho-Substitution
with a Sulfonyl Group. Mailyan, A.K; Geraskin, I.M.; Nemykin, V.N.;
Zhdankin, V.V. J. Org. Chem.
2009, 74, 8444-8447.
Iodine(V)/Ruthenium(III)-Cocatalyzed Oxidations: A Highly Efficient
Tandem Catalytic System for the Oxidation of Alcohols and Hydrocarbons
with Oxone. Yusubov, M.S.; Zagulyaeva, A.A.; Zhdankin, V.V. Chem. Eur. J. 2009, 15, 11091-11094.
Oligomeric iodosylbenzene sulfate, (PhIO)3•SO3: Convenient hypervalent
iodine reagent for oxidation of organic sulfides and alkenes. Yusubov,
M.S.; Yusubova, M.S.; Funk, T.V.; Chi, K.-W.; Zhdankin, V.V. Synthesis 2009, 2505-2508.
Self-assembly of hydroxy(phenyl)iodonium ions in acidic aqueous
solution: preparation, and X-ray crystal structures of oligomeric
phenyliodine(III) sulfates. Nemykin, V.N.; Koposov, A.Y.; Netzel, B.C.;
Yusubov, M.S.; Zhdankin, V.V. Inorg.
Chem. 2009, 48, 4908-4917.
Comparative Reactivity of Hypervalent Iodine Oxidants in
Metalloporphyrin-Catalyzed Oxygenation of Hydrocarbons: Iodosylbenzene
Sulfate and 2-Iodylbenzoic Acid Ester as Safe and Convenient
Alternatives to Iodosylbenzene. Geraskin, I.M.; Pavlova, O.; Neu, H.M.;
Yusubov, M.S.; Nemykin, V.N.; Zhdankin, V.V. Adv. Synth. Cat. 2009, 351, 733-737.
Hypervalent Iodine(III) Reagents in Organic Synthesis. Zhdankin, V.V. ARKIVOC 2009, (i), 1-62.
Chemistry of Polyvalent Iodine. Zhdankin, V.V.; Stang, P.J. Chem. Rev. 2008, 108, 5399-5358.
Preparation and X-ray crystal structure of 2-iodyl-N,N-dialkylaniline
oxides: first entry into the heterocyclic system of benziodoxazole.
Zhdankin, V.V.; Nemykin, V.N.; Karimov, R.R.; Kazhkenov, Z.M. Chem. Commun. 2008, 6131-6133.
Organic iodine(V) compounds as terminal oxidants in iron(III)
phthalocyanine catalyzed oxidation of alcohols. Geraskin, I.M.;
Luedtke, M.W.; Neu, H.M.; Nemykin, V.N.; Zhdankin, V.V. Tetrahedron Lett. 2008, 49, 7410-7412.
Synthesis of Tricyclic Phosphono Pyrrolidines via IMDAF: Experimental
and Theoretical Investigation of the Observed Stereoselectivity.
Claeys, D.D.; Moonen, K.; Roman, B.I.; Nemykin, V.N.; Zhdankin, V.V.;
Waroquier, M.; Speybroeck, V.V.; Stevens, C.V. J. Org. Chem. 2008, 73, 7921-7927.
Comprehensive
Heterocyclic Chemistry III, Volume 5 (10 chapters): “Triazoles,
Oxadiazoles, Thiadiazoles and their Fused Carbocyclic Derivatives,”
V.V. Zhdankin, Ed.; Elsevier, Oxford, 2008.
Comprehensive Heterocyclic Chemistry III, Volume 6 (18 chapters):
“Other Five-Membered Rings with Three or More Heteroatoms and their
Fused Carbocyclic Derivatives,” V.V. Zhdankin, Ed.; Elsevier, Oxford,
2008.
Heterocycles with Three or Four Heteroatoms Including At Least One
Phosphorus. Zhdankin, V.V. In Comprehensive Heterocyclic Chemistry III.
Katritzky, A.R.; Ramsden, C.A.; Scriven, E.F.V.; Taylor, R.J.K., Eds.;
Elsevier, Oxford, 2008, Vol. 6, Chapter 13, pp 583-602.
Preparation
and X-ray Structures of 3-[Bis(trifluoroacetoxy)iodo]benzoic acid and
3-[Hydroxy(tosyloxy)iodo]benzoic acid, New Recyclable Hypervalent
Iodine Reagents. Yusubov, M.S.; Funk, T.V.; Chi, K.-W.; Cha, E.-H.;
Ghyung, H.K.; Kirschning, A.; Zhdankin, V.V. J. Org. Chem. 2008, 73, 295-297.
Preparation
and Reactivity of Polymer-Supported 2-Iodylphenol Ethers,
an Efficient Recyclable Oxidizing System. Karimov, R.R.; Kazhkenov,
Z.M.; Modjewski, M.J.; Peterson, E.M.; Zhdankin, V.V. J. Org. Chem. 2007, 72, 8149-8151.
Preparation
and Structure of Oligomeric Iodosylbenzene Sulfate (PhIO)3•SO3: Stable
and Water-soluble Analog of Iodosylbenzene. Koposov, A.Y.; Netzel,
B.C.; Yusubov, M.S.; Nemykin, V.N.; Nazarenko, A.Y.; Zhdankin, V.V. Eur. J. Org. Chem. 2007, 4475-4478.
Hypervalent
Iodoarenes and
Aryliodonium Salts. Zhdankin, V.V. Science
of Synthesis, 2007, 31, Ch. 31.4.1, 161-234.
N-(2-Iodylphenyl)acylamides
- New Pentavalent Iodine Oxidizing Reagents. Ladziata, U.; Zhdankin,
V.V. Synlett 2007, 527-537.
m-Iodosylbenzoic
Acid as a Convenient Recyclable Reagent for Highly Efficient
RuCl3-Catalyzed Oxidation of Alcohols to Carbonyl Compounds. Yusubov,
M.S.; Gilmkhanova, M.P.; Zhdankin, V.V.; Kirschning, A. Synlett 2007, 563-566.
trans Influences on
Hypervalent Bonding of Aryl λ3-Iodanes: Their Stabilities and Isodesmic
Reactions of Benziodoxolones and Benziodazolones. Ochiai, M.; Sueda,
T.; Miyamoto, K.; Kiprof, P.; Zhdankin, V.V. Angew. Chem. Int. Ed. 2006, 45, 8203-8206.
Hypervalent
Iodine(V) Reagents in Organic Synthesis. Ladziata,
U.; Zhdankin, V.V. ARKIVOC 2006, (ix), 26-58.
Facile
Preparation and Reactivity of Polymer-Supported
N-(2-Iodyl-phenyl)-acylamide,
an Efficient Oxidizing System. Ladziata,
U.; Willging, J.; Zhdankin, V.V. Org.
Lett. 2006, 7, 167-170.
Highly
Efficient RuCl3-Catalyzed Disproportionation of
(Diacetoxyiodo)benzene to Iodylbenzene and Iodobenzene; Leading to the
Efficient Oxidation of Alcohols to Carbonyl Compounds. Yusubov, M.S.;
Chi, K.-W.; Park, J.Y.; Karimov, R.; Zhdankin, V.V. Tetrahedron Lett. 2006, 47, 6305-6308.
Synthesis and Oxidative Reactivity of New Chiral Hypervalent Iodine(V)
Reagents Based on (S)-Proline. Ladziata, U.; Carlson, J.; Zhdankin,
V.V. Tetrahedron Lett. 2006, 47, 6301-6304.
Preparation and Reductive Decomposition of
2-Iodoxybenzenesulfonic Acid; X-Ray Crystal Structure of 1H-1-Hydroxy-1,2,3-benziodoxathiole
3,3-dioxide. Koposov, A.Y.; Litvinov, D.N.; Zhdankin, V.V.; Ferguson,
M.J.; McDonald, R.; Tykwinski, R.R. Eur.
J. Org. Chem. 2006,
4791-4795.
2-Iodylphenol Ethers: Preparation, X-Ray Crystal Structure, and
Reactivity of New Hypervalent Iodine(V) Oxidizing Reagents. Koposov,
A.Y.; Karimov, R.R.; Geraskin, I.; Nemykin, V.N.; Zhdankin, V.V. J. Org. Chem. 2006, 71, 8452-8458.
RuCl3-catalyzed Oxidation of Iodoarenes with Peracetic Acid:
New Facile Preparation of Iodylarenes. Koposov, A.Y.; Karimov, R.R.;
Pronin, A.A.; Skrupskaya, T.; Yusubov, M.S.; Zhdankin, V.V. J. Org. Chem. 2006, 71, 9912-9914.
Selective Oxidation of Sulfides to Sulfoxides Using IBX-Esters.
Koposov, A.Y.; Zhdankin, V.V. Synthesis
2005, 22-25.
Derivatives of 2-Iodoxybenzenesulfonic Acid: New Pseudocyclic
Hypervalent Iodine Reagents. Zhdankin, V.V.; Goncharenko, R.N.;
Litvinov, D.N.; Koposov, A.Y. ARKIVOC
2005, (4), 8-18.
Benziodoxole-Based Hypervalent Iodine Reagents in Organic
Synthesis. Zhdankin, V.V. Curr. Org.
Synth. 2005, 2, 121-145.
Esters of 2-Iodoxybenzoic Acid (IBX-Esters): Hypervalent Iodine
Oxidizing Reagents with a Pseudobenziodoxole Structure. Zhdankin, V.V.;
Koposov, A.Y.; Litvinov, D.N.; Ferguson, M.J.; McDonald, R.; Luu, T.;
Tykwinski, R.R. J. Org. Chem. 2005, 70, 6484-6491.
Intra- and Intermolecular Interactions in the Solid State Structure of
2-Iodylbenzenesulfonamides: a Heptacoordinated Organic Iodine(V)
Compound. Koposov, A.Y.; Nemykin, V.N.; Zhdankin, V.V. New J. Chem. 2005, 29, 998-1000.
Synthesis, Structure and Chemoselective Reactivity of
N-(2-Iodylphenyl)-acylamides, Novel Hypervalent Iodine Reagents Bearing
Pseudo Six-membered Ring Scaffold. Ladziata, U.; Koposov, A.Y.; Lo,
K.Y.; Willging, J.; Nemykin, V.N.; Zhdankin, V.V. Angew. Chem. Int. Ed. 2005, 44, 7127-7131.
Alkynyl Halides and Chalcogenides. Zhdankin, V.V. In Comprehensive
Organic Functional Group Transformations II. Katritzky, A.R.;
Taylor, R.J.K., Eds.; Elsevier, Oxford, 2004, Vol. 2, Chapter 21,
1073-1114.
Preparation and Structure of 2-Iodoxybenzoate Esters: Soluble and
Stable Periodinane Oxidizing Reagents. Zhdankin, V.V.; Litvinov, D.N.;
Koposov, A.Y.;
Luu, T.; Ferguson, M.J.; McDonald, R.; Tykwinski, R.R. J. Chem.
Soc.,
Chem. Commun. 2004, 106-107.
2-Iodoxybenzenesulfamides: New Pseudobenziodoxole-Based
Hypervalent Iodine Reagents. Koposov, A.Y.; Litvinov, D.N.; Zhdankin,
V.V. Tetrahedron Lett. 2004, 45, 2719-2721.
4,4'-Bis(dichloroiodo)biphenyl and 3-(Dichloroiodo)benzoic
Acid: New Recyclable Hypervalent Iodine Reagents for Vicinal
Halomethoxylation of Unsaturated Compounds. Yusubov, M.S.; Drygunova,
L.A.; Zhdankin, V.V. Synthesis
2004, 2289-2292.
Amino acid-derived iodobenzene dicarboxylates: Reagents for
oxidative conversion of alkenes to amino acid esters. Koposov, A.Y.;
Boyarskikh, V.V.; Zhdankin, V.V. Org. Lett. 2004, 6, 3613-3615.
C–C Bond Forming Reactions. Zhdankin, V.V. In Topics in
Current Chemistry, Vol. 224, Wirth, T., Ed.; Springer-Verlag,
Berlin Heidelberg, 2003, Chapter 4, pp. 99-136.
Preparation and
Chemistry of Phosphorane-Derived Iodanes.
Zhdankin, V.V.; Maydanovych, O.; Herschbach, J.; Bruno, J.; Matveeva,
E.D.; Zefirov, N.S. J. Org. Chem. 2003, 68,
1018-1023.
IBX Amides: New
Family of Hypervalent Iodine Reagents. Zhdankin, V.V.;
Koposov, A.Y.; Netzel, B.C.; Yashin, N.V.; Rempel, B.P.; Ferguson,
M.J.; Tykwinski, R.R. Angew. Chem. Int. Ed. 2003, 42,
2194-2196. (Placed on Angew. Chem. Hot Articles Website).
Synthesis and
Structure of Amino Acid-Derived Benziodazoles: New
Hypervalent Iodine Heterocycles. Zhdankin, V.V.; Koposov, A.Y.; Su, L.;
Boyarskikh,
V.V.; Netzel, B.C.; Young, V.G. Org. Lett. 2003, 5,
1583-1586. (Placed on ACS Hot Articles Website).
Recent Developments in the Chemistry of Polyvalent
Iodine Compounds. Zhdankin, V.V.; Stang, P.J. Chem. Rev. 2002,
102, 2523-2584.
Complexes of
Hypervalent Iodine Compounds with
Nitrogen Ligands. Zhdankin, V.V.; Koposov, A.Y.; Yashin, N.V. Tetrahedron
Lett. 2002, 42, 5735-5737.
Preparation,
Structure, and Unexpected Chemistry of
Phosphoranyl Derived Benziodoxoles. Zhdankin, V.V.; Maydanovych, O.;
Herschbach, J.; Tykwinski, R.R.; McDonald, R. J. Am. Chem. Soc.
2002, 124, 11614-11615.
Functionalization
of Buckminsterfullerene by
Hypervalent Iodine Reagents. Zhdankin, V.V.; Hanson, K.J.; Koposov,
A.E.; Blomquist, E.; Tykwinski, R.R. Mendeleev Commun. 2001,
51-52.
Secondary
Bonding-Directed Self-Assembly of Amino
Acid Derived Benziodazoles: Synthesis and Structure of Novel
Hypervalent Iodine Macrocycles. Zhdankin, V.V.; Koposov, A.E.; Smart,
J.T.; Tykwinski, R.R.; McDonald, R.; Morales-Izquierdo, A. J. Am.
Chem. Soc. 2001, 123, 4095-4096.
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